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Dielectric Constant: Common Materials and Solutions

Dielectric Constant of common materials

Material

Dielectric Constant

Air

1.00058986±0.00000050
(at STP, 900 kHz)

Ammonia

26, 22, 20, 17 (−80, −40, 0, +20 °C)

Calcium copper titanate

>250,000

Carbon disulfide

2.6

Concrete

4.5

Conjugated polymers

1.8–6 up to 100,000

Diamond

5.5–10

Electroactive polymers

2–12

Ethylene glycol

37

GaAs

12.4

Graphite

10–15

Hydrocyanic acid

158.0–2.3 (0–21 °C)

Hydrofluoric acid

175, 134, 111, 83.6
(−73, −42, −27, 0 °C),

Hydrogen peroxide

128 aqueous–60
(−30–25 °C)

Melamine resin

7.2–8.4

Methanol

30

Mica

3–6

Natural rubber

7

Paper, printing

1.4 (200 kHz)

Polyethylene/XLPE

2.25

PTFE/Teflon

2.1

Pyrex (glass)

4.7 (3.7–10)

Salt

3–15

Sapphire

8.9–11.1 (anisotropic)

Silicon

11.68

Silicon dioxide

3.9

Silicon nitride

7–8 (polycrystalline, 1 MHz)

Silicone rubber

2.9–4

Sulfuric acid

84–100 (20–25 °C)

Vacuum

1

Water

87.9, 80.2, 55.5
(0, 20, 100 °C)
for visible light: 1.77

Note: The dielectric constants mentioned above are measured at room temperature under 1 kHz. [1]

Dielectric Constant of common solvents

Solvent

Dielectric Constant

Temperature

Acetal

3.7 - 3.9

298 K (25 °C)

Acetic Acid

6.2

293 K (20 °C)

Acetone

20.7

298 K (25 °C)

Acetonitrile

37.5

293 K (20 °C)

Acrylic

2.1-3.9

298 K (25 °C)

Benzene

2.3

298 K (25 °C)

Dichloromethane

9.1

293 K (20 °C)

Diethyl ether

4.3

293 K (20 °C)

Dimethyl formamide (DMF)

36.7

298 K (25 °C)

Ethanol

24.3

298 K (25 °C)

Ether

4.3

293 K (20 °C)

Fluorine refrigerant R-12

2

298 K (25 °C)

Fluorine refrigerant R-22

2

298 K (25 °C)

Formamide

109

293 K (20 °C)

Liquid ammonia

17

273 K (0 °C)

Methanol

32.7

298 K (25 °C)

Nitromethane

35.9

303 K (30 °C)

Tetrahydrofuran (THF)

7.6

298 K (25 °C)

Water

78.4

298 K (25 °C)

 

Dielectric Constant: FAQs

1. What is the dielectric constant?

The dielectric constant, also known as relative permittivity, measures a substance's ability to store electrical energy in an electric field. It compares the ability of a material to insulate charges relative to a vacuum.

2. How is the dielectric constant calculated?

It's determined by dividing the capacitance of a capacitor filled with a substance by the capacitance of the same capacitor in a vacuum or air. Mathematically, it's expressed as ε = C/C₀, where ε is the dielectric constant, C is the capacitance with the substance, and C₀ is the capacitance in vacuum.

3. Are Dielectric Constant and Dielectric Strength the Same?

No, they're different. The dielectric constant measures a material's ability to store electric energy, while dielectric strength indicates the maximum electric field a material can withstand before electrical breakdown occurs.

4. Why is the dielectric constant important?

It's crucial in various fields, especially in determining the behavior of materials in electric fields, aiding in capacitor design, understanding solvation effects in chemistry, and analyzing the properties of materials in electronics.

5. What influences the dielectric constant?

Factors like molecular structure, polarity, and interactions between molecules significantly impact a substance's dielectric constant. Polar substances generally have higher dielectric constants than non-polar ones.

6. Can dielectric constant vary with temperature and pressure?

Yes, dielectric constants can change with alterations in temperature and pressure. Changes in these parameters can impact molecular interactions and, subsequently, a substance's ability to store electric charge.

7. How does the dielectric constant affect solvation?

The dielectric constant influences a solvent's ability to dissolve ionic compounds. High dielectric constant solvents are excellent for dissolving salts and polar molecules due to their ability to separate and stabilize ions.

8. What are some practical applications of dielectric constants?

Dielectric constants find applications in various industries, including electronics for capacitor design, chemistry solvent selection, material sciences for understanding material properties, and the study of biomolecular interactions.

 

 

Reference:

[1] Relative permittivity. (2023, November 23). In Wikipedia. https://en.wikipedia.org/wiki/Relative_permittivity

About the author

Chin Trento

Chin Trento holds a bachelor’s degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years in Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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