SECTION 1. IDENTIFICATION
Product Name: Carbonyldihydridotris(triphenylphosphine)ruthenium(II)
CAS #: 25360-32-1
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
OSHA Haz Com: CFR 1910.1200: Acute Toxicity - Oral [Category 4]
Signal word: Warning!
Hazard Statement(s): Harmful if swallowed
Pictogram(s) or Symbol(s):
Precautionary Statement(s):
[Prevention] Do not eat, drink or smoke when using this product. Wash hands and face thoroughly
after handling.
[Response] If swallowed: Immediately call a poison center or doctor. Rinse mouth.
[Storage] None
[Disposal] Dispose of contents and container in accordance with US EPA guidelines for the
classification and
determination of hazardous waste listed in 40 CFR 261.3. (See Section 13)
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Mixture: Substance
Components: Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)
Percent: ....
CAS Number: 25360-32-1
Molecular Weight: 917.97
Chemical Formula: C55H47OP3Ru
SECTION 4. FIRST AID MEASURES
Inhalation: Call a poison center or doctor if you feel unwell. Move victim to fresh air. Give artificial
respiration if victim
is not breathing. Administer oxygen if breathing is difficult. Keep victim warm and quiet. Treat
symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved
and
take precautions to protect themselves.
Skin contact: Call a poison center or doctor if you feel unwell. Remove and isolate contaminated
clothing and shoes. In
case of contact with substance, immediately flush skin with running water for at least 20 minutes. Treat
symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved
and
take precautions to protect themselves.
Eye contact: If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large
amounts of water,
occasionally lifting the lower and upper eyelids. If eye irritation persists get medical advice/attention.
Move
victim to fresh air. Check for and remove any contact lenses. Keep victim warm and quiet. Treat
symptomatically and supportively. Effects of exposure to substance may be delayed. Ensure that
medical
personnel are aware of the material(s) involved and take precautions to protect themselves.
Ingestion: Harmful if swallowed. If swallowed, seek medical advice immediately and show the
container or label. Do
not use mouth-to-mouth method if victim ingested the substance; give artificial respiration with the aid
of a
pocket mask equipped with a one-way valve or other proper respiratory medical device. Loosen tight
clothing such as a collar, tie, belt or waistband. If a person vomits place them in the recovery position
so
that vomit will not reenter the mouth and throat. Rinse mouth. Keep victim warm and quiet. Treat
symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved
and
take precautions to protect themselves.
Symptoms/effects:
Acute: No data available
Delayed: No data available
Immediate medical attention: WARNING: It might be hazardous to the person providing aid to give
mouth-to-mouth respiration, because
the inhaled material is harmful. If breathing has stopped, perform artificial respiration. Use first aid
treatment according to the nature of the injury. Ensure that medical personnel are aware of the
material(s)
involved and take precautions to protect themselves.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media: Dry chemical, CO2 , sand, earth, water spray or regular foam Consult
with local fire authorities before
attempting large scale fire fighting operations.
Specific hazards arising from the chemical
Hazardous combustion products: These products include: Carbon oxides Phosphates Metallic oxides
Other specific hazards: Closed containers may explode from heat of a fire.
Special precautions for fire-fighters:
Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not
scatter the material. Containers may explode when
heated. Move containers from fire area if you can do it without risk.
Special protective equipment for fire-fighters:
Wear positive pressure self-contained breathing apparatus (SCBA). Structural fire fighters' protective
clothing provides limited protection in fire situations
ONLY; it may not be effective in spill situations. Wear chemical protective clothing which is specifically
recommended by the manufacturer. It may
provide little or no thermal protection.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Avoid contact with skin, eyes, and clothing. Keep people away from and upwind
of spill/leak. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing (Section 8).
Warn
unnecessary personnel to move away. Stop leak if you can do it without risk. Ensure adequate
ventilation.
Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Personal protective equipment: Safety glasses. Lab coat. Dust respirator. Be sure to use a
MSHA/NIOSH approved respirator or
equivalent. Wear protective gloves (nitrile).
Emergency procedures: Prevent dust cloud. In case of a spill and/or a leak, always shut off any
sources of ignition, ventilate the
area, and excercise caution. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Warn personnel to move away. Prevent entry into sewers, basements
or
confined areas; dike if needed.
Methods and materials for containment and cleaning up:
ELIMINATE all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if
without risk. Ventilate the area. Absorb with an
inert material and put the spilled material in an appropriate waste disposal container. Use clean non-
sparking tools to collect absorbed material.
Environmental precautions:
Keep away from living quarters. Prevent further leakage or spillage if safe to do so. Water runoff can
cause environmental damage. Prevent entry into
sewers, basements or confined areas; dike if needed.
SECTION 7. HANDLING AND STORAGE
Precautions for safe handling: Avoid inhalation of vapor or mist. Do not ingest. Avoid contact with skinand eyes. Good general ventilation
should be sufficient to control airborne levels. Keep container dry. Handle and open container with
care.
Wear suitable protective clothing, gloves and eye/face protection. When using do not eat, drink, or
smoke.
Keep away from sources of ignition.
Conditions for safe storage: Keep only in the original container in a cool well-ventilated place. Keep
away from incompatibles.
Containers which are opened must be carefully resealed and kept upright to prevent leakage. Avoid
prolonged storage periods. Store under inert gas (e.g. Argon). Moisture sensitive. Store in refrigerator.
Storage incompatibilities: Store away from oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limits: No data available
Appropriate engineering controls:
Good general ventilation should be sufficient to control airborne levels. Ventilation is normally required
when handling or using this product. Eyewash
fountains should be provided in areas where there is any possibility that workers could be exposed to
the substance. Follow safe industrial
engineering/laboratory practices when handling any chemical.
Personal protective equipment
Respiratory protection: Dust respirator. Be sure to use a MSHA/NIOSH approved respirator or
equivalent.
Hand protection: Wear protective gloves.
Eye protection: Safety glasses.
Skin and body protection: Lab coat.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C): Solid
Form: Crystal - Powder
Color: White - Very pale yellow
Odor: No data available
Odor threshold: No data available
Melting point/freezing point: 163°C (325°F)
Boiling point/range: No data available
Decomposition temperature: No data available
Relative density: No data available
Kinematic Viscosity: No data available
Partition coefficient: No data available
n-octanol/water (log Pow)
Flash point: No data available
Flammability (solid, gas): No data available
pH: No data available
Vapor pressure: No data available
Vapor density: No data available
Dynamic Viscosity: No data available
Evaporation rate: No data available
(Butyl Acetate = 1)Autoignition temperature: No data available
Flammability or explosive limits: No data available
Lower: No data available
Upper: No data available
Solubility(ies):
SECTION 10. STABILITY AND REACTIVITY
Reactivity: Not Available.
Chemical Stability: Heat sensitive. Moisture sensitive.
Possibility of Hazardous Reactions: No hazardous reactivity has been reported.
Conditions to avoid: Exposure to moisture. Heat sensitive. Moisture sensitive.
Incompatible materials: Strong oxidizing agents
Hazardous Decomposition Products: No data available
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity:
No data available
Skin corrosion/irritation:
No data available
Serious eye damage/irritation:
No data available
Respiratory or skin sensitization:
No data available
Germ cell mutagenicity:
No data available
Carcinogenicity:
No data available
IARC: No data available NTP: No data available OSHA: No data available
Reproductive toxicity:
No data available
Routes of Exposure: Inhalation, Eye contact, Ingestion.
Symptoms related to exposure:
Overexposure may result in serious illness or death.
Potential Health Effects:
No specific information available; skin and eye contact may result in irriatation. May be harmful if
inhaled or ingested.
Target organ(s): No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Fish: No data available
Crustacea: No data available
Algae: No data available
Persistence and degradability: No data available
Bioaccumulative potential (BCF): No data available
Mobillity in soil: No data availablePartition coefficient:
n-octanol/water (log Pow)
No data available
Soil adsorption (Koc): No data available
Henry's Law:
constant (PaM3/mol)
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal of product: Recycle to process if possible. It is the generator's responsibility to comply with
Federal, State and Local
rules and regulations. You may be able to dissolve or mix material with a combustible solvent and burn
in a
chemical incinerator equipped with an afterburner and scrubber system. This section is intended to
provide
assistance but does not replace these laws, nor does compliance in accordance with this section
ensure
regulatory compliance according to the law. US EPA guidelines for Identification and Listing of
Hazardous
Waste are listed in 40 CFR Parts 261. The product should not be allowed to enter the environment,
drains,
water ways, or the soil.
Disposal of container: Dispose of as unused product. Do not re-use empty containers.
Other considerations: Observe all federal, state and local regulations when disposing of the
substance.
SECTION 14. TRANSPORT INFORMATION
DOT (US) Non-hazardous for transportation.
IATA Non-hazardous for transportation.
IMDG Non-hazardous for transportation.
SECTION 15. REGULATORY INFORMATION
Toxic Substance Control Act (TSCA 8b.):
This product is NOT on the EPA Toxic Substances Control Act (TSCA) inventory. The following
notices are required by 40 CFR 720.36 (C) for those
products not on the inventory list:
(i) These products are supplied solely for use in research and development by or under the
supervision of a technically qualified individual as defined in
40 CFR 720.0 et sec.
(ii) The health risks of these products have not been fully determined. Any information that is or
becomes available will be supplied on a SDS sheet.
US Federal Regulations
CERCLA Hazardous substance and Reportable Quantity:
SARA 313: Not Listed
SARA 302: Not Listed
State Regulations
State Right-to-KnowMassachusetts Not Listed
New Jersey Not Listed
Pennsylvania Not Listed
California Proposition 65: Not Listed
Other Information
NFPA Rating:
Health: 1
Flammability: 0
Instability: 0
HMIS Classification:
Health: 1
Flammability: 0
Physical: 0
International Inventories
WHMIS hazard class: D2A: Materials causing other toxic effects. (Very Toxic)
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
ruthenium.jpg)
