BM1288 Boron Crystalline Powder (B)

SECTION 1. IDENTIFICATION

Product Name: Boron Powder

CAS #: 7440-42-8

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

GHS02 Flame

Flam. Sol. 2 H228 Flammable solid.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Acute Tox. 4 H332 Harmful if inhaled.

STOT SE 3 H335 May cause respiratory irritation.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xn; Harmful

R20/22: Harmful by inhalation and if swallowed.

Xi; Irritant

R37: Irritating to respiratory system.

F; Highly flammable

R11: Highly flammable.

Information concerning particular hazards for human and environment:

N/A

Hazards not otherwise classified

No data available.

Label elementsLabelling according to Regulation (EC) No 1272/2008

The substance is classified and labeled according to the CLP regulation.

Hazard pictograms

GHS02 GHS07

Signal word: Warning

Hazard statements

H228 Flammable solid.

H302+H332 Harmful if swallowed or if inhaled.

H335 May cause respiratory irritation.

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P261 Avoid breathing dust/fume/gas/mist/vapors/spray.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

WHMIS classification

B4 - Flammable solid

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

HEALTH

FIRE

REACTIVITY

2

2

1

Health (acute effects) = 2

Flammability = 2

Physical Hazard = 1

Other hazards

Results of PBT and vPvB assessment:

PBT: N/A.

vPvB: N/A.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS No. / Substance Name:

7440-42-8 Boron

Identification number(s):

EC number: 231-151-2

SECTION 4. FIRST AID MEASURES

Description of first aid measuresIf inhaled:

Supply fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Seek medical treatment.

Information for doctor

Most important symptoms and effects, both acute and delayed

No information available.

Indication of any immediate medical attention and special treatment needed

No information available.

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Special powder for metal fires. Do not use water.

For safety reasons unsuitable extinguishing media

Water

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Boron oxide

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Keep away from ignition sources

Environmental precautions:

Do not allow material to be released to the environment without official permits.

Do not allow product to reach sewage system or any water course.

Do not allow to penetrate the ground/soil.

Methods and material for containment and cleanup:

Keep away from ignition sources.

Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

Keep away from ignition sources.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure adequate ventilation.

Information about protection against explosions and fires:

Protect against electrostatic charges.

Conditions for safe storage, including any incompatibilities

Storage

Requirements to be met by storerooms and receptacles:

Store in a cool location.

Information about storage in one common storage facility:

Do not store together with acids.

Store away from oxidizing agents.

Store away from halogens.

Store away from ammonia

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Specific end use(s)

No information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and

having an average face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values

that should be monitored at the workplace.

Additional information: No data

Exposure controls

Personal protective equipment

Follow typical general protective and industrial hygiene measures for handling chemicals.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Breathing equipment:

Use suitable respirator when high concentrations are present.

Recommended filter device for short term use:

Use a respirator with type N95 (USA) or PE (EN 143) cartridges as a backup to engineering controls.

Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only

use equipment tested and approved under appropriate government standards.

Protection of hands: Impervious gloves

Inspect gloves prior to use.

Suitability of gloves should be determined both by material and quality, the latter of which may vary by

manufacturer.

Material of glovesButyl rubber, BR

Penetration time of glove material (in minutes)

No data available.

Eye protection: Safety glasses

Body protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form: Solid in various forms

Color: No data available.

Odor: Odorless

Odor threshold: No data available.

pH: N/A.

Melting point/range: 2075 °C (3767 °F)

Boiling point/range: 2550 °C (4622 °F)

Sublimation temperature / start: No data available.

Flammability (solid, gas):

Highly flammable.

Ignition temperature: 700 °C (1292 °F)

Decomposition temperature: No data available.

Auto igniting: No data available.

Danger of explosion: No data available.

Explosion limits:

Lower: No data available.

Upper: No data available.

Vapor pressure: N/A.

Density at 20 °C (68 °F): 2.34 g/cm³ (19.527 lbs/gal)

Relative density: No data available.

Vapor density: N/A.

Evaporation rate: N/A.

Solubility in Water (H

2

O): Insoluble

Partition coefficient (n-octanol/water): No data available.

Viscosity:

Dynamic: N/A.

Kinematic: N/A.

Other information

No further relevant information available

SECTION 10. STABILITY AND REACTIVITY

Reactivity: No data available.

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

Reacts with strong oxidizing agents

Conditions to avoid

No information available.Incompatible materials:

Acids

Oxidizing agents

Halogens

Ammonia

Hazardous decomposition products:

Boron oxide

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

N/A

LD/LC50 values that are relevant for classification:

No data

Skin irritation or corrosion:

Causes skin irritation.

Eye irritation or corrosion:

Causes serious eye irritation.

Sensitization:

No sensitizing effects known.

Germ cell mutagenicity:

N/A

Carcinogenicity:

No classification data on carcinogenic properties of this material is available from the EPA, IARC,

NTP, OSHA or ACGIH.

Reproductive toxicity:

N/A

Specific target organ system toxicity - repeated exposure:

N/A

Specific target organ system toxicity - single exposure:

May cause respiratory irritation.

Aspiration hazard:

N/A

Subacute to chronic toxicity:

Titanium and titanium compounds are considered physiologically inert. There are no reported cases in

the literature where titanium as such has caused human intoxication.

Subacute to chronic toxicity:

N/A

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

Carcinogenic categories

OSHA-Ca (Occupational Safety & Health Administration)

Substance is not listed.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No information available.

Persistence and degradability:No information available.

Bioaccumulative potential:

No information available.

Mobility in soil:

No information available.

Additional ecological information:

General notes:

Do not allow material to be released to the environment without official permits.

Do not allow undiluted product or large quantities to reach ground water, water course or sewage

system.

Avoid transfer into the environment.

Results of PBT and vPvB assessment:

PBT: N/A.

vPvB: N/A.

Other adverse effects

No information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation:

Consult state, local or national regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA

UN3178

UN proper shipping name

DOT

Flammable solid, inorganic, n.o.s. (Boron powder)

IMDG, IATA

FLAMMABLE SOLID, INORGANIC, N.O.S. (Boron powder)

Transport hazard class(es)

DOT

Label

4.1

Class

4.1 (F3) Flammable solids, self-reactive substances and solid desensitised explosives

Label

4.1

IMDG, IATA

Class

4.1 Flammable solids, self-reactive substances and solid desensitised explosives.

Label

4.1

Packing group

DOT, IMDG, IATAIII

Environmental hazards:

N/A.

Special precautions for user

Warning: Flammable solids, self-reactive substances and solid desensitised explosives

EMS Number:

F-A,S-G

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N/A.

Transport/Additional information:

DOT

Marine Pollutant (DOT):

No

UN "Model Regulation":

UN3178, Flammable solid, inorganic, n.o.s. (Boron powder), 4.1, III

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Domestic Substances List (DSL).

SARA Section 313 (specific toxic chemical listings)

Substance is not listed.

California Proposition 65

Prop 65 - Chemicals known to cause cancer

Substance is not listed.

Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

For use only by technically qualified individuals.

Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

Substance is not listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the

market and use must be observed.

Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

Substance is not listed.

REACH - Pre-registered substances

Substance is listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.