RH2122 Tris(triphenylphosphine)rhodium(I) Chloride Powder (CAS No.14694-95-2)

Catalog No.	RH2122
CAS Number	14694-95-2
Molecular Formula	C54H45ClP3Rh
Molecular Weight	925.22

Stanford Advanced Materials uses its experience and expertise to provide the highest quality precious metal compounds. We offer high purity tris(triphenylphosphine)rhodium(I) chloride powder according to your requirements.

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Description

Specification

Technical Data Sheet

Description of Tris(triphenylphosphine)rhodium(I) Chloride Powder

Tris(triphenylphosphine)rhodium(I) Chloride is one of numerous organo-metallic compounds.

Specification of Tris(triphenylphosphine)rhodium(I) Chloride Powder

Compound Formula	C₅₄H₄₅ClP₃Rh^-
Molecular Weight	925.22
Appearance	Red to Brown Powder
Melting Point	254-250 °C
Boiling Point	N/A
Density	N/A
Solubility in H2O	Insoluble
Exact Mass	924.147768
Monoisotopic Mass	924.147768
Charge	-1

Application of Tris(triphenylphosphine)rhodium(I) Chloride Powder

Hydrosilylation Catalysts

Catalyst used for many organic reactions including:
• Chemoselective allylic alkylations
• Stoichiometric activation of Si-H bonds and hydrosilylations
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst
• Polymerization of diorganostannanes
Useful catalyst for the efficient cross-coupling of activated alkenyl tosylates with arylboronic acids.[1] Also used to catalyze the cleavage of allyl phenolic ethers to phenols with DABCO.

FAQs

Q1. What is Tris(triphenylphosphine)rhodium(I) Chloride Powder used for?

Tris(triphenylphosphine)rhodium(I) Chloride Powder is primarily used as a catalyst in organic synthesis, particularly in hydrogenation reactions, carbon-carbon bond-forming reactions, and various other catalysis processes. It is highly effective in promoting reactions that require rhodium-based catalysis.

Q2. What are the key components of Tris(triphenylphosphine)rhodium(I) Chloride Powder?

This compound consists of a rhodium(I) center coordinated with three triphenylphosphine ligands and one chloride ion. The triphenylphosphine ligands enhance the reactivity of the rhodium center, making it an efficient catalyst.

Q3. Is Tris(triphenylphosphine)rhodium(I) Chloride Powder stable?

Yes, it is generally stable under normal conditions. However, it should be stored in a dry, inert atmosphere (such as nitrogen or argon) to prevent oxidation or decomposition.