SECTION 1. IDENTIFICATION
Product Name: Rhodium(III) Iodide
CAS #: 15492-38-3
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
Hazards not otherwise classified
No information known.
Label elements
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS08
Signal word
Warning
Hazard statements
H341 Suspected of causing genetic defects.
Precautionary statements
P281Use personal protective equipment as required.
P201
Obtain special instructions before use.
P202
Do not handle until all safety precautions have been read and understood.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Substances
CAS# Description:
15492-38-3 Rhodium(III) iodide
Identification number(s):
EC number: 239-521-5
SECTION 4. FIRST AID MEASURES
Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Hydrogen iodide (HI)
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from water/moisture.
Store away from oxidizing agents.
Further information about storage conditions:
Store under dry inert gas.
This product is hygroscopic.Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Protect from humidity and water.
Specific end use(s)
No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary
from manufacturer to manufacturer.
Penetration time of glove material (in minutes)
Not determined
Eye protection:
Safety glasses
Body protection:
Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form: Crystalline
Color: Black
Odor: Odorless
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: Not determinedBoiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density: Not determined
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Insoluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No further relevant information available.
Incompatible materials:
Water/moisture
Oxidizing agents
Hazardous decomposition products:
Hydrogen iodide (HI)
Metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data forcomponents in this product.
LD/LC50 values that are relevant for classification:
Oral LD50 >5000 mg/kg (rat)
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
Suspected of causing genetic defects.
Carcinogenicity:
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on
which to classify the agent in terms of its carcinogenicity in humans and/or animals.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
No effects known.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, ADN, IMDG, IATA
Not applicable
UN proper shipping name
DOT, ADN, IMDG, IATA
Not applicable
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class
Not applicable
Packing group
DOT, IMDG, IATA
Not applicable
Environmental hazards:
Not applicable.
Special precautions for user
Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS08
Signal word
Warning
Hazard statements
H341 Suspected of causing genetic defects.
Precautionary statements
P281
Use personal protective equipment as required.
P201
Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
GHS07