HF3280 Hafnium Oxide Powder, HfO2 (CAS No. 12055-23-1)

SECTION 1. IDENTIFICATION

Product Name: Hafnium Oxide

CAS #: 12055-23-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

The substance is not classified as hazardous to health or the environment according to the CLP

regulation.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC

N/A

Information concerning particular hazards for human and environment:

No data available

Hazards not otherwise classified

No data available

Label elements

Labelling according to Regulation (EC) No 1272/2008

N/A

Hazard pictograms

N/A

Signal word

N/A

Hazard statements

N/A

WHMIS classificationNot controlled

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

HEALTH

FIRE

REACTIVITY

1

0

0

Health (acute effects) = 1

Flammability = 0

Physical Hazard = 0

Other hazards

Results of PBT and vPvB assessment

PBT:

N/A

vPvB:

N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS No. / Substance Name:

12055-23-1 Hafnium(IV) oxide

Identification number(s):

EC number:

235-013-2

Additional information:

Hafnium is routinely found with a low level of zirconium since separation of the two elements is

difficult.

SECTION 4. FIRST AID MEASURES

Description of first aid measures

If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Seek medical treatment.

Information for doctor

Most important symptoms and effects, both acute and delayed

No data available

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Product is not flammable. Use fire-fighting measures that suit the surrounding fire.

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Metal oxide fume

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Environmental precautions:

Do not allow material to be released to the environment without official permits.

Do not allow product to enter drains, sewage systems, or other water courses.

Do not allow material to penetrate the ground or soil.

Methods and materials for containment and cleanup:

Pick up mechanically.

Prevention of secondary hazards:

No special measures required.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Information about protection against explosions and fires:

The product is not flammable

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles:

No special requirements.

Information about storage in one common storage facility:

Store away from oxidizing agents.

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and having an average

face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

12055-23-1 Hafnium(IV) oxide (100.0%)

PEL (USA) Long-term value: 0.5 mg/m

3

as Hf

REL (USA) Long-term value: 0.5 mg/m

3

as Hf

TLV (USA) Long-term value: 0.5 mg/m

3

as Hf

EL (Canada) Long-term value: 0.5 mg/m

3

as Hf

Additional information:

No data

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Use suitable respirator when high concentrations are present.

Recommended filter device for short term use:

Use a respirator with type N95 (USA) or PE (EN 143) cartridges as a backup to engineering cont

rols. Risk assessment should be performed to determine if air-

purifying respirators are appropriate. Only use equipment tested and approved under appropriate

government standards.

Protection of hands:

Impervious gloves

Inspect gloves prior to use.

Suitability of gloves should be determined both by material and quality, the latter of which may vary by

manufacturer.

Material of gloves

Nitrile rubber, NBR

Penetration time of glove material (in minutes)

No data available

Eye protection:

Safety glasses

Body protection:

Protective work clothing

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:Form: Pieces

Color: Off-white

Odor: Odorless

Odor threshold: No data available.

pH: N/A

Melting point/Melting range: 2774 °C (5025 °F)

Boiling point/Boiling range: No data available

Sublimation temperature / start: No data available

Flammability (solid, gas)

No data available.

Ignition temperature: No data available

Decomposition temperature: No data available

Autoignition: No data available.

Danger of explosion: No data available

Explosion limits:

Lower: No data available

Upper: No data available

Vapor pressure: N/A

Density at 20 °C (68 °F): 9.68 g/cm

3

(80.78 lbs/gal)

Relative density

No data available.

Vapor density

N/A

Evaporation rate

N/A

Solubility in Water (H

2

O): Insoluble

Partition coefficient (n-octanol/water): No data available.

Viscosity:

Dynamic: N/A

Kinematic: N/A

Other information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

Reacts with strong oxidizing agents

Conditions to avoid

No data available

Incompatible materials:

Oxidizing agents

Hazardous decomposition products:

Metal oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

No effects known.

LD/LC50 values that are relevant for classification:

No data

Skin irritation or corrosion:

May cause irritation

Eye irritation or corrosion:

May cause irritation

Sensitization: No sensitizing effects known.

Germ cell mutagenicity: No effects known.

Carcinogenicity:

No classification data on carcinogenic properties of this material is available from the EPA, IARC,

NTP, OSHA or ACGIH.

Reproductive toxicity: No effects known.

Specific target organ system toxicity - repeated exposure: No effects known.

Specific target organ system toxicity - single exposure: No effects known.

Aspiration hazard: No effects known.

Subacute to chronic toxicity: No effects known.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Additional ecological information:

Do not allow material to be released to the environment without official permits.

Avoid transfer into the environment.

Results of PBT and vPvB assessment

PBT:

N/A

vPvB:

N/A

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation

Consult official regulations to ensure proper disposal.

Uncleaned packagings:Recommendation:

Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, ADN, IMDG, IATA

N/A

UN proper shipping name

DOT, ADN, IMDG, IATA

N/A

Transport hazard class(es)

DOT, ADR, ADN, IMDG, IATA

Class

N/A

Packing group

DOT, IMDG, IATA

N/A

Environmental hazards: N/A

Special precautions for user

N/A

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N/A

Transport/Additional information: DOT

Marine Pollutant (DOT): No

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Domestic Substances List (DSL).

SARA Section 313 (specific toxic chemical listings)

Substance is not listed.

California Proposition 65

Prop 65 - Chemicals known to cause cancer

Substance is not listed.

Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

For use only by technically qualified individuals.

Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

Substance is not listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

Substance is not listed.

REACH - Pre-registered substances

Substance is listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.