Ytterbium Chloride (CAS No. 19423-87-1) | Stanford Advanced Materials

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Ytterbium

Ytterbium Compound

CL1536 Ytterbium Chloride Powder (CAS No. 19423-87-1)

Catalog No.	CL1536
CAS Number	19423-87-1
Appearance	White crystalline
Chemical Formula	YbCl3.xH2O
Density	4.06 g/cm3
Melting Point	854 °C
Solubleness	Soluble in water, moderately soluble in strong min
Molecular Weight	279.40 (anhy)
Stability	Slightly hygroscopic

Stanford Advanced Materials (SAM) is a leading supplier of ytterbium chloride. SAM also provides ytterbium metal and ytterbium compounds to our customers.

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Description

Specification

Technical Data Sheet

Ytterbium Chloride Description

Ytterbium Chloride is applied to numerous fiber amplifiers and fiber optic technologies, High purity grades are widely applied as a doping agent for garnet crystals in lasers an important colorant in glasses and porcelain enamel glazes. Ytterbium chloride is a powerful catalyst for the formation of acetals using trimethyl orthoformate. YbCl3 may be used as a calcium ion probe, in a fashion similar to a sodium ion probe, it is also used to track digestion in animals.

Ytterbium Chloride Specification

Product Code	CL70-5N	CL70-4N	CL70-3N
Grade	99.999%	99.99%	99.9%
CHEMICAL COMPOSITION
Yb2O3 /TREO (% min.)	99.999	99.99	99.9
TREO (% min.)	45	45	45
Rare Earth Impurities	ppm max.	ppm max.	% max.
Tb4O7/TREO Dy2O3/TREO Ho2O3/TREO Er2O3/TREO Tm2O3/TREO Lu2O3/TREO Y2O3/TREO	1 1 1 5 5 1 3	5 20 20 25 30 50 20	0.005 0.005 0.005 0.010 0.010 0.050 0.005
Non-Rare Earth Impurities	ppm max.	ppm max.	% max.
Fe2O3 SiO2 CaO NiO ZnO PbO	3 15 15 2 3 2	15 50 100 5 10 5	0.002 0.01 0.02 0.001 0.001 0.001

Ytterbium Chloride Application

Laser Gain Medium: Ytterbium chloride is used as a precursor for the production of ytterbium-doped laser gain media. Ytterbium-doped laser crystals or glasses are employed in solid-state lasers to generate high-power laser beams, particularly in the near-infrared (NIR) region. These lasers find applications in materials processing, cutting, welding, and scientific research.

Fiber Lasers: Ytterbium-doped optical fibers are used as gain media in ytterbium-doped fiber lasers. These lasers are known for their high efficiency and excellent beam quality, making them valuable in industrial and research applications, including materials processing and telecommunications.

Medical Lasers: Ytterbium lasers are used in various medical applications, such as laser surgery and dermatology, for precise tissue ablation and medical treatments.

Materials Processing: Ytterbium lasers are employed for cutting, welding, engraving, and marking materials like metals, ceramics, and polymers in industrial manufacturing processes.

Spectroscopy: Ytterbium-doped materials are used as sources of laser light in analytical techniques like laser-induced breakdown spectroscopy (LIBS) and laser-induced fluorescence (LIF) for elemental analysis and material characterization.

Optical Amplifiers: Ytterbium-doped optical amplifiers are used in optical communication systems to amplify optical signals in long-haul fiber-optic networks. They are essential for efficient data transmission over long distances.

Frequency Conversion: Ytterbium-doped materials are used for frequency conversion processes, such as second-harmonic generation (SHG) and parametric amplification, to generate laser light at different wavelengths, including visible and ultraviolet (UV) regions.

Quantum Optics: Ytterbium ions in solid-state systems are studied for their potential applications in quantum optics, including quantum computing and quantum information processing.

Nuclear and Particle Physics: Ytterbium-doped materials are used as detectors in nuclear and particle physics experiments due to their sensitivity to ionizing radiation.

Research and Development: Ytterbium chloride is utilized in scientific research and development in various fields, including physics, chemistry, and materials science, for its unique optical and laser properties.

Energy Storage: Ytterbium-doped materials are studied for their potential use in energy storage systems, such as ytterbium-doped lithium niobate for optical data storage.

Ytterbium Chloride Packaging

Our Ytterbium Chloride Powder is clearly tagged and labeled externally to ensure efficient identification and quality control. Great care is taken to avoid any damage which might be caused during storage or transportation.

Ytterbium Chloride Safety Information

Signal Word	Warning
Hazard Statements	H315-H319-H335
Hazard Codes	Xi
Precautionary Statements	P261-P305 + P351 + P338
Flash Point	Not applicable
Risk Codes	36/37/38
Safety Statements	26-36
RTECS Number	ZG2100000
Transport Information	NONH for all modes of transport
WGK Germany	2
GHS Pictograms

Specification

Product Code	CL70-5N	CL70-4N	CL70-3N
Grade	99.999%	99.99%	99.9%
CHEMICAL COMPOSITION
Yb2O3 /TREO (% min.)	99.999	99.99	99.9
TREO (% min.)	45	45	45
Rare Earth Impurities	ppm max.	ppm max.	% max.
Tb4O7/TREO Dy2O3/TREO Ho2O3/TREO Er2O3/TREO Tm2O3/TREO Lu2O3/TREO Y2O3/TREO	1 1 1 5 5 1 3	5 20 20 25 30 50 20	0.005 0.005 0.005 0.010 0.010 0.050 0.005
Non-Rare Earth Impurities	ppm max.	ppm max.	% max.
Fe2O3 SiO2 CaO NiO ZnO PbO	3 15 15 2 3 2	15 50 100 5 10 5	0.002 0.01 0.02 0.001 0.001 0.001

Technical Data Sheet

SDS

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SAFETY DATA SHEET

SECTION 1. IDENTIFICATION

Product Name: Ytterbium Chloride

CAS #: 10035-01-5

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Skin irritation(Category 2), H315

Eye irritation(Category 2A), H319

Specific target organ toxicity -single exposure(Category 3), Respiratory system, H335

GHS Label elements, including precautionary statements

Pictogram

Signal word

Warning

Hazard statement(s)

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H335May cause respiratory irritation.

Precautionary statement(s)

P261

Avoid breathing dust/ fume/ gas/ mist/ Vapors/ spray.

P264

Wash skin thoroughly after handling.

P271

Use only outdoors or in a well-ventilated area.

P280

Wear protective gloves/ eye protection/ face protection.

P302 + P352

IF ON SKIN:

Wash with plenty of soap and water.

P304 + P340

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305 + P351 + P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.

P312

Call a POISON CENTER or doctor/ physician if you feel unwell.

P321

Specific treatment (see supplemental first aid instructions on this label).

P332 + P313

If skin irritation occurs: Get medical advice/ attention.

P337 + P313

If eye irritation persists: Get medical advice/ attention.

P362

Take off contaminated clothing and wash before reuse.

P403 + P233

Store in a well-ventilated place. Keep container tightly closed.

P405

Store locked up.

P501

Dispose of contents/ container to an approved waste disposal plant.

Hazards not otherwise classified (HNOC) or not covered by GHS-none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula: Cl3Yb 6H2O

Molecular Weight: 387.49 g/mol

CAS-No.: 10035-01-5

EC-No.: 237-632-3

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

Move out of dangerous area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult aphysician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute a

nd delayed

The most important known symptoms and effects are described in the labelling (see section 2) and/or

in section 11

Indication of any immediate medical attention and special treatment needed

no data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Hydrogen chloride gas, ytterbium oxides

Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

no data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure

adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed

containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed.

For precautions see section 2.

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place.

Keep in a dry place.

Specific end use(s)Apart from the uses mentioned in section 1 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Contains no substances with occupational exposure limit values.

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks

and at the end of workday.

Personal protective equipment

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and

approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and

good laboratory practices. Wash and dry hands.

Body Protection

impervious clothing, The type of protective equipment must be selected according to the concentration

and amount of the dangerous substance at the specific workplace.

Respiratory protection

For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level

protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use

respirators and components tested and approved under appropriate government standards such as

NIOSH (US) or CEN (EU).

Control of environmental exposure

Do not let product enter drains.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Form: powder

Odor

no data available

Odor Threshold

no data available

Melting point/freezing point

Melting point/range: 180 °C (356 °F)-dec.

Initial boiling point and boiling range

no data available

Flash point

not applicable

EVaporation rate

no data available

Flammability (solid, gas)no data available

Upper/lower flammability or explosive limits

no data available

Vapor pressure

no data available

Vapor density

no data available

Relative density

2.58 g/mL at 25 °C (77 °F)

Water solubility

no data available

Partition coefficient: n-octanol/water

no data available

Auto-ignition temperature

no data available

Decomposition temperature

no data available

Viscosity

no data available

Explosive properties

no data available

Oxidizing properties

no data available

Other safety information

no data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

no data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

no data available

Conditions to avoid

Avoid moisture.

Incompatible materials

Strong oxidizing agents

Hazardous decomposition products

Other decomposition products-no data available

In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

no data available

Dermal: no data available

no data available

Skin corrosion/irritation

no data availableSerious eye damage/eye irritation

no data available

Respiratory or skin sensitisation

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC:

No component of this product present at levels greater than or equal to 0.1%

is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH:

No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by ACGIH.

NTP:

No component of this product present at levels greater than or equal to 0.1% is identified as a

known or anticipated carcinogen by NTP.

OSHA:

No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by OSHA.

Reproductive toxicity

no data available

Specific target organ toxicity -single exposure

Inhalation-May cause respiratory irritation.

Specific target organ toxicity -repeated exposure

no data available

Aspiration hazard

no data available

Additional Information

RTECS: Not available

Rare earth compounds may cause delayed blood clotting leading to hemorrhages. Inhalation of rare

earths may cause sensitivity to heat, itching, and increased awareness of odor and taste., To the best

of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly

investigated.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.

Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging

Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)

Not dangerous goods

IMDG

Not dangerous goods

IATA

Not dangerous goods

SECTION 15. REGULATORY INFORMATION

SARA 302 Components

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 Components

SARA 313: This material does not contain any chemical components with known CAS numbers that

exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards

Acute Health Hazard

Massachusetts Right To Know Components

No components are subject to the Massachusetts Right to Know Act.

Pennsylvania Right To Know Components

Ytterbium(III) chloride hexahydrate

CAS-No.

10035-01-5

New Jersey Right To Know Components

Ytterbium(III) chloride hexahydrate

CAS-No.

10035-01-5

California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth

defects, or any other reproductive harm.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.

COA

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COA

Purity	wt%
YbCl3.xH2O	99.99

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CL1536 Ytterbium Chloride Powder (CAS No. 19423-87-1)

Ytterbium Chloride Description

Ytterbium Chloride Specification

Ytterbium Chloride Application

Ytterbium Chloride Packaging

Ytterbium Chloride Safety Information

Specification

Technical Data Sheet

SAFETY DATA SHEET

SECTION 1. IDENTIFICATION

SECTION 2. HAZARDS IDENTIFICATION

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

SECTION 4. FIRST AID MEASURES

SECTION 5. FIREFIGHTING MEASURES

SECTION 6. ACCIDENTAL RELEASE MEASURES

SECTION 7. HANDLING AND STORAGE

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

SECTION 10. STABILITY AND REACTIVITY

SECTION 11. TOXICOLOGICAL INFORMATION

SECTION 12. ECOLOGICAL INFORMATION

SECTION 13. DISPOSAL CONSIDERATIONS

SECTION 14. TRANSPORT INFORMATION

SECTION 15. REGULATORY INFORMATION

SECTION 16. OTHER INFORMATION

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