SECTION 1. IDENTIFICATION
Product Name: Vanadium(IV) Oxide Sulfate Hydrate
CAS #: 123334-20-3
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral(Category 4), H302
GHS Label elements, including precautionary statements
Pictogram
Signal word
Warning
Hazard statement(s)
H302
Harmful if swallowed.
Precautionary statement(s)
P264
Wash skin thoroughly after handling.
P270
Do not eat, drink or smoke when using this product.P301 + P312
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P330
Rinse mouth.
P501
Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS-none
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Synonyms: Vanadyl sulfate hydrate
Formula: O5SV xH2O
Molecular Weight:163.00 g/mol
CAS-No.: 123334-20-3
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a
physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or
in section 11
Indication of any immediate medical attention and special treatment needed
no data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Sulphur oxides, Vanadium/vanadium oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure
adequate ventilation. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.
SECTION 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for
preventive fire protection.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Handle and store under inert gas.
Hygroscopic.
Keep in a dry place.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Component
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Value
C
Control parameters
0.05 mg/m3
Basis
USA. NIOSH Recommended Exposure Limits
Remarks
15 minute ceiling value
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks
and at the end of workday.
Personal protective equipmentEye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by
an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our
customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level
protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use
respirators and components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance
Form: powder
Colour: blue
Odor
no data available
Odor Threshold
no data available
pH
no data available
Melting point/freezing point
Melting point/range: 105 °C (221 °F)-lit.
Initial boiling point and boiling range
no data available
Flash point
not applicable
EVaporation rate
no data available
Flammability (solid, gas)no data available
Upper/lower flammability or explosive limits
no data available
Vapor pressure
no data available
Vapor density
no data available
Relative density
no data available
Water solubility
no data available
Partition coefficient: n-octanol/water
no data available
Auto-ignition temperature
no data available
Decomposition temperature
no data available
Viscosity
no data available
Explosive properties
no data available
Oxidizing properties
no data available
Other safety information
no data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
no data available
Conditions to avoid
Avoid moisture.
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products-no data available
In the event of fire: see section 5
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Inhalation: no data available
Dermal: no data available
no data available
Skin corrosion/irritationno data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity -single exposure
no data available
Specific target organ toxicity -repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Stomach-Irregularities-Based on Human Evidence
Stomach-Irregularities-Based on Human Evidence
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped
with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
SECTION 14. TRANSPORT INFORMATION
DOT (US)
UN number: 2931
Class: 6.1
Packing group: II
Proper shipping name: Vanadyl sulfate
Reportable Quantity
(RQ): 1000 lbs
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 2931
Class: 6.1
Packing group: II
EMS-No: F-A, S-A
Proper shipping name: VANADYL SULPHATE
Marine pollutant: No
IATA
UN number:2931
Class: 6.1
Packing group: II
Proper shipping name: Vanadyl sulphate
SECTION 15. REGULATORY INFORMATION
SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,
Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Revision Date
1993-04-24
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
Vanadium oxide sulphate hydrate
CAS-No.123334-20-3
Revision Date
1993-04-24
Pennsylvania Right To Know Components
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Revision Date
1993-04-24
New Jersey Right To Know Components
Vanadium oxide sulphate hydrate
CAS-No.
123334-20-3
Revision Date
1993-04-24
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
