VS1739 Vanadium(IV) Oxide Sulfate Hydrate Powder (CAS No. 123334-20-3)

SECTION 1. IDENTIFICATION

Product Name: Vanadium(IV) Oxide Sulfate Hydrate

CAS #: 123334-20-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Acute toxicity, Oral(Category 4), H302

GHS Label elements, including precautionary statements

Pictogram

Signal word

Warning

Hazard statement(s)

H302

Harmful if swallowed.

Precautionary statement(s)

P264

Wash skin thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.P301 + P312

IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.

P330

Rinse mouth.

P501

Dispose of contents/ container to an approved waste disposal plant.

Hazards not otherwise classified (HNOC) or not covered by GHS-none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Synonyms: Vanadyl sulfate hydrate

Formula: O5SV xH2O

Molecular Weight:163.00 g/mol

CAS-No.: 123334-20-3

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

Move out of dangerous area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a

physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2) and/or

in section 11

Indication of any immediate medical attention and special treatment needed

no data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Sulphur oxides, Vanadium/vanadium oxides

Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

no data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure

adequate ventilation. Avoid breathing dust.

For personal protection see section 8.

Environmental precautions

Do not let product enter drains.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed

containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for

preventive fire protection.

For precautions see section 2.

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place.

Handle and store under inert gas.

Hygroscopic.

Keep in a dry place.

Specific end use(s)

Apart from the uses mentioned in section 1 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Components with workplace control parameters

Component

Vanadium oxide sulphate hydrate

CAS-No.

123334-20-3

Value

C

Control parameters

0.05 mg/m3

Basis

USA. NIOSH Recommended Exposure Limits

Remarks

15 minute ceiling value

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks

and at the end of workday.

Personal protective equipmentEye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and

approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0.11 mm

Break through time: 480 min

Splash contact

Material: Nitrile rubber

Minimum layer thickness: 0.11 mm

Break through time: 480 min

If used in solution, or mixed with other substances, and under conditions which differ from EN 374,

contact the

supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by

an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our

customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected

according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level

protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use

respirators and components tested and approved under appropriate government standards such as

NIOSH (US) or CEN (EU).

Control of environmental exposure

Do not let product enter drains.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Form: powder

Colour: blue

Odor

no data available

Odor Threshold

no data available

pH

no data available

Melting point/freezing point

Melting point/range: 105 °C (221 °F)-lit.

Initial boiling point and boiling range

no data available

Flash point

not applicable

EVaporation rate

no data available

Flammability (solid, gas)no data available

Upper/lower flammability or explosive limits

no data available

Vapor pressure

no data available

Vapor density

no data available

Relative density

no data available

Water solubility

no data available

Partition coefficient: n-octanol/water

no data available

Auto-ignition temperature

no data available

Decomposition temperature

no data available

Viscosity

no data available

Explosive properties

no data available

Oxidizing properties

no data available

Other safety information

no data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

no data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

no data available

Conditions to avoid

Avoid moisture.

Incompatible materials

Strong oxidizing agents

Hazardous decomposition products

Other decomposition products-no data available

In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

no data available

Inhalation: no data available

Dermal: no data available

no data available

Skin corrosion/irritationno data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitisation

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC:

No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

ACGIH:

No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by ACGIH.

NTP:

No component of this product present at levels greater than or equal to 0.1% is identified as a

known or anticipated carcinogen by NTP.

OSHA:

No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by OSHA.

Reproductive toxicity

no data available

no data available

Specific target organ toxicity -single exposure

no data available

Specific target organ toxicity -repeated exposure

no data available

Aspiration hazard

no data available

Additional Information

RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not been

thoroughly investigated.

Stomach-Irregularities-Based on Human Evidence

Stomach-Irregularities-Based on Human Evidence

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability

no data available

Bioaccumulative potential

no data available

Mobility in soil

no data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.

Contact a licensed professional waste disposal service to dispose of this material.

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped

with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)

UN number: 2931

Class: 6.1

Packing group: II

Proper shipping name: Vanadyl sulfate

Reportable Quantity

(RQ): 1000 lbs

Marine pollutant: No

Poison Inhalation Hazard: No

IMDG

UN number: 2931

Class: 6.1

Packing group: II

EMS-No: F-A, S-A

Proper shipping name: VANADYL SULPHATE

Marine pollutant: No

IATA

UN number:2931

Class: 6.1

Packing group: II

Proper shipping name: Vanadyl sulphate

SECTION 15. REGULATORY INFORMATION

SARA 302 Components

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 Components

The following components are subject to reporting levels established by SARA Title III, Section 313:

Vanadium oxide sulphate hydrate

CAS-No.

123334-20-3

Revision Date

1993-04-24

SARA 311/312 Hazards

Acute Health Hazard, Chronic Health Hazard

Massachusetts Right To Know Components

Vanadium oxide sulphate hydrate

CAS-No.123334-20-3

Revision Date

1993-04-24

Pennsylvania Right To Know Components

Vanadium oxide sulphate hydrate

CAS-No.

123334-20-3

Revision Date

1993-04-24

New Jersey Right To Know Components

Vanadium oxide sulphate hydrate

CAS-No.

123334-20-3

Revision Date

1993-04-24

California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth

defects, or any other reproductive harm.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.