SECTION 1. IDENTIFICATION
Product Name: Sodium Tetrachloroplatinate(II) Hydrate
CAS #: 207683-21-4
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS06 Skull and crossbones
Acute Tox. 2 H300 Fatal if swallowed.
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Hazards not otherwise classified No information known.
Label elements
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA
HCS)
Hazard pictograms
GHS05 GHS06 GHS08
Signal word Danger
Hazard statements
H300 Fatal if swallowed.
H315 Causes skin irritation.H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
Precautionary statements
P284 In case of inadequate ventilation wear respiratory protection.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor/…
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
WHMIS classification
D1A - Very toxic material causing immediate and serious toxic effects
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Substances
CAS# Description:
207683-21-4 Sodium tetrachloroplatinate (II)
Identification number(s):
EC number: 233-051-4
Index number: 078-003-00-1
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Do not induce vomiting; immediately call for medical help.
Information for doctor
Most important symptoms and effects, both acute and delayed No further relevant informationavailable.
Danger
Platinum compounds, especially platinum halogen complexes, are sensitizers. Sensitized persons, on
re-exposure to platinum salts, will show the clinical features of
a Type 1 allergy: asthma and/or rhinitis and/or conjunctivitis and/or urticaria. A contact dermatitis may
also occur. The symptoms of the allergic reaction to platinum
salts may include any of the following: itchy red eyes, watering of the eyes, sneezing, runny nose,
chest tightness, wheezing, breathlessness, cough, eczematous or
urticarial (nettle rash type) skin lesions. Exposure to platinum salts in exceedingly small amounts, even
below the level of
physico-chemical detection, will produce symptoms in sensitized persons. Continued exposure will
give symptoms of increasing severity and can eventually lead to
chronic asthma. There is a risk of anaphylactic shock occuring in sensitized persons re-encountering
platinum salts. Therefore, if sensitization has developed, further
exposure to platinum compounds must not be permitted.
Indication of any immediate medical attention and special treatment needed No further relevant
information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents Carbon dioxide, extinguishing powder or water spray. Fight larger fires
with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Hydrogen chloride (HCl)
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without proper
governmental permits.
Methods and material for containment and cleaning up: Dispose of contaminated material as waste
according to section 13.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
HandlingPrecautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Prevent formation of dust.
Information about protection against explosions and fires: The product is not flammable
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s) No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
Platinum metal and soluble salts (as Pt)
mg/m3
ACGIH TLV 1 (metal); 0.002 (soluble salts)
Austria MAK 1 (metal); 0.002 (soluble salts)
Belgium TWA 1 (metal); 0.002 (soluble salts)
Denmark TWA 0.002 (soluble salts)
Finland TWA 1 (metal); 0.002 (soluble salts)
France VME 1 (metal)
Germany MAK 0.002 (soluble salts)-Ceiling
Hungary TWA 0.001; 0.002-STEL (soluble salts)
Korea TLV 1 (metal); 0.002 (soluble salts)
Netherlands MAC-TTG 1 (metal); 0.002 (soluble salts)
Norway TWA 0.002
Switzerland MAK-W 0.002
United Kingdom TWA 5 (metal); 0.002 (soluble salts)
USA PEL 0.002
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will varyfrom manufacturer to manufacturer.
Eye protection: Tightly sealed goggles
Body protection: Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form: Crystalline
Color: Red
Odor: Not determined
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 100 °C (212 °F)
Boiling point/Boiling range: 150 °C (302 °F)
Sublimation temperature / start: Not determined
Flash point: Not applicable
Flammability (solid, gaseous) Not determined.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density: Not determined
Relative density Not determined.
Vapor density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
Water: Soluble
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information No further relevant information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity No information known.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored
according to specifications.
Possibility of hazardous reactions No dangerous reactions known
Conditions to avoid No further relevant information available.
Incompatible materials: Oxidizing agents
Hazardous decomposition products:
Hydrogen chloride (HCl)Metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity: Fatal if swallowed.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: Causes skin irritation.
Eye irritation or corrosion:
Irritating effect.
Causes serious eye damage.
Sensitization:
Platinum salts, especially ionic platinum halogeno complexes, may cause severe allergic reactions.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Germ cell mutagenicity: No effects known.
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the
EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
The toxicity of sodium compounds is generally due to the anion.
Exposure to platinum containing dusts or fumes may cause irritation, sensitization reactions and
asthma. Effects include sneezing, coughing, tightness in the chest,
dyspnea and wheezing. Cyanosis is possible. Chronic exposure may result in pulmonary fibrosis.
Subacute to chronic toxicity: No effects known.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage
system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agent: Water, if necessary with cleansing agents.
SECTION 14. TRANSPORT INFORMATION
Not a hazardous material for transportation.
UN-Number
DOT, IMDG, IATA None
UN proper shipping name
DOT, IMDG, IATA None
Transport hazard class(es)
DOT, ADR, IMDG, IATA
Class None
Packing group
DOT, IMDG, IATA None
Environmental hazards: Not applicable.
Special precautions for user Not applicable.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information: Not dangerous according to the above specifications.
DOT
Marine Pollutant (DOT): No
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA
HCS)
Hazard pictograms
GHS05 GHS06 GHS08
Signal word Danger
Hazard statements
H300 Fatal if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
Precautionary statements
P284 In case of inadequate ventilation wear respiratory protection.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor/…
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency ToxicSubstances Control Act Chemical substance Inventory.
SARA Section 313 (specific toxic chemical listings) Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use: For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
