PA2443 Trans-Dibromo[bis(tri-o-tolylphosphine)] Palladium(II) Powder CAS 24554-43-6

SECTION 1. IDENTIFICATION

Product Name: trans-Dichlorobis(triphenylphosphine)palladium(II)

CAS #: 13965-03-2

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Not a hazardous substance or mixture.

2.2 GHS Label elements, including precautionary statements

Not a hazardous substance or mixture.

2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances

Synonyms : Palladium(II)bis(triphenylphosphine) dichloride

Dichlorobis(triphenylphosphine)palladium(II)

PdCl2(PPh3)2

Formula : C36H30Cl2P2Pd

Molecular Weight : 701.90 g/mol

CAS-No. : 13965-03-2

EC-No. : 237-744-2

No ingredients are hazardous according to OSHA criteria.

No components need to be disclosed according to the applicable regulations

SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration.

In case of skin contact

Wash off with soap and plenty of water.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2)

and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

no data available

SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture

Carbon oxides, Oxides of phosphorus, Hydrogen chloride gas

5.3 Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further information

no data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing Vapors, mist or gas.

For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Sweep up and shovel. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling

Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for

preventive fire protection.

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilitiesStore under nitrogen. Keep container tightly closed in a dry and well-ventilated place.

hygroscopic Handle under nitrogen, protect from moisture. Store under nitrogen.

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Components with workplace control parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Appropriate engineering controls

General industrial hygiene practice.

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such

as

NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without

touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves

after

use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0.11 mm

Break through time: 480 min

Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)

Splash contact

Material: Nitrile rubber

Minimum layer thickness: 0.11 mm

Break through time: 480 min

Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test

method:

EN374

If used in solution, or mixed with other substances, and under conditions which differ from EN 374,

contact the

supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by

an

industrial hygienist and safety officer familiar with the specific situation of anticipated use by our

customers. It

should not be construed as offering an approval for any specific use scenario.

Body Protection

Choose body protection in relation to its type, to the concentration and amount of dangerous

substances, and

to the specific work-place., The type of protective equipment must be selected according to the

concentration

and amount of the dangerous substance at the specific workplace.

Respiratory protection

Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use

typeN95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved

under

appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure

Do not let product enter drains.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

a) Appearance Form: crystalline

Colour: yellow

b) Odor no data available

c) Odor Threshold no data available

d) pH no data available

e) Melting point/freezing

point

no data available

f) Initial boiling point and

boiling range

no data available

g) Flash point no data available

h) EVaporation rate no data available

i) Flammability (solid, gas) no data available

j) Upper/lower

flammability or

explosive limits

k) Vapor pressure no data available

l) Vapor density no data available

m) Relative density no data available

n) Water solubility no data available

o) Partition coefficient: noctanol/

water

no data available

p) Auto-ignition

temperature

no data available

q) Decomposition

temperature

no data available

r) Viscosity no data available

s) Explosive properties no data available

t) Oxidizing properties no data available

9.2 Other safety information

no data available

SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity

no data available

10.2 Chemical stability

Heat.Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

Exposure to moisture.

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

Other decomposition products - no data available

In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity

no data available

Inhalation: no data available

Dermal: no data available

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitisation

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as

probable, possible or confirmed human carcinogen by IARC.

ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by ACGIH.

NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a

known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by OSHA.

Reproductive toxicity

no data available

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Additional Information

RTECS: Not available

To the best of our knowledge, the chemical, physical, and toxicological properties have not been

thoroughly

investigated.

SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity

no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

12.6 Other adverse effects

no data available

SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.

Contaminated packaging

Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)

Not dangerous goods

IMDG

Not dangerous goods

IATA

Not dangerous goods

SECTION 15. REGULATORY INFORMATION

SARA 302 Components

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 Components

SARA 313: This material does not contain any chemical components with known CAS numbers that

exceed the

threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards

No SARA Hazards

Massachusetts Right To Know Components

No components are subject to the Massachusetts Right to Know Act.

Pennsylvania Right To Know Components

Dichlorobis(triphenylphosphine)palladium

CAS-No.

13965-03-2

Revision DateNew Jersey Right To Know Components

Dichlorobis(triphenylphosphine)palladium

CAS-No.

13965-03-2

Revision Date

California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth

defects, or any other

reproductive harm.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.