NR1908 Manganese Nitride (Mn3N2) Powder (CAS No. 36678-21-4)

SECTION 1. IDENTIFICATION

Product Name: Manganese(II) Nitrate

CAS #: 10377-66-9

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)

GHS03 Flame over circle

Ox. Liq. 2 H272 May intensify fire; oxidizer.

GHS08 Health hazard

STOT RE 2 H373 May cause damage to the brain through prolonged or repeated exposure. Route of

exposure: Inhalative.

GHS05 Corrosion

Skin Corr. 1C H314 Causes severe skin burns and eye damage.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Hazards not otherwise classified No data available

GHS label elements, including precautionary statementsHazard pictograms

GHS03 GHS05 GHS07 GHS08

Signal word Danger

Hazard-determining components of labeling:

Manganese(II) nitrate

Hazard statements

H272 May intensify fire; oxidizer.

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.

H373 May cause damage to the brain through prolonged or repeated exposure. Route of exposure:

Inhalative.

Precautionary statements

P221 Take any precaution to avoid mixing with combustibles.

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with

water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

WHMIS classification

D1B - Toxic material causing immediate and serious toxic effects

D2A - Very toxic material causing other toxic effects

E - Corrosive material

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

HEALTH

FIRE

REACTIVITY

3

0

2

Health (acute effects) = 3

Flammability = 0

Physical Hazard = 2

Other hazards

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Mixtures

Dangerous components:

10377-66-9 Manganese(II) nitrate

Ox. Sol. 2, H272; STOT RE 2, H373; Skin Corr. 1C, H314; Eye Dam. 1, H318; Acute Tox. 4, H302

50.0%

Additional information None known.Non-Hazardous Ingredients

7732-18-5 Water

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General information Immediately remove any clothing soiled by the product.

If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Seek medical treatment.

Information for doctor

Most important symptoms and effects, both acute and delayed

Causes severe skin burns.

Causes serious eye damage.

Indication of any immediate medical attention and special treatment needed:

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the

surrounding fire.

For safety reasons unsuitable extinguishing agents Halocarbon extinguisher

Special hazards arising from the substance or mixture

This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause

ignition.

If this product is involved in a fire, the following can be released:

Nitrogen oxides (NOx)

Metal oxide fume

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Environmental precautions: Do not allow product to enter drains, sewage systems, or other water

courses.

Methods and materials for containment and cleanup:

Use neutralizing agent.Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Absorb with liquid-binding material.

Prevention of secondary hazards:

Acts as an oxidizing agent on organic materials such as wood, paper and fats

Keep away from combustible material.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.

Information about protection against explosions and fires:

Substance/product can reduce the ignition temperature of flammable substances.

This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause

ignition.

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles: No special requirements.

Information about storage in one common storage facility:

Store away from flammable substances.

Store away from reducing agents.

Do not store with organic materials.

Store away from metal powders.

Store away from strong bases.

Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many

reactive organic and inorganic chemicals.

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Specific end use(s) No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and having an average

face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

10377-66-9 Manganese(II) nitrate (50.0%)

PEL (USA) Ceiling limit value: 5 mg/m

3

as Mn

REL (USA) Short-term value: 3 mg/m

3

Long-term value: 1 mg/m

3

as MnTLV (USA) Long-term value: 0.02* 0.1* mg/m

3

as Mn; *respirable **inhalable fraction

EL (Canada) Long-term value: 0.2 mg/m

3

as Mn; R

Additional information: No data

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Do not inhale dust / smoke / mist.

Avoid contact with the eyes and skin.

Maintain an ergonomically appropriate working environment.

Breathing equipment: Use suitable respirator when high concentrations are present.

Recommended filter device for short term use:

Use a respirator with acid gas cartridges as a backup to engineering controls. Risk assessment should

be performed to determine if air-purifying respirators are

appropriate. Only use equipment tested and approved under appropriate government standards such

as NIOSH (USA) or CEN (EU).

Protection of hands:

Impervious gloves

Inspect gloves prior to use.

The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary

from manufacturer to manufacturer.

Penetration time of glove material (in minutes) Not determined

Eye protection:

Tightly sealed goggles

Full face protection

Body protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form: Liquid

Color: Pink

Odor: Amine-like

Odor threshold: Not determined.

pH at 20 °C (68 °F): 1 (approx)

Melting point/Melting range: Not determined

Boiling point/Boiling range: Not determined

Sublimation temperature / start: Not determined

Flammability (solid, gas) Not determined.

Ignition temperature: Not determined

Decomposition temperature: Not determined

Autoignition: Product is not selfigniting.

Danger of explosion: Not determined.

Explosion limits:

Lower: Not determined

Upper: Not determined

Vapor pressure at 20 °C (68 °F): 23 hPa (17 mm Hg)Density at 20 °C (68 °F): 1.54 g/cm

3

(12.851 lbs/gal)

Relative density Not determined.

Vapor density Not determined.

Evaporation rate Not determined.

Solubility in / Miscibility with

Water: Fully miscible

Partition coefficient (n-octanol/water): Not determined.

Viscosity:

Dynamic: Not determined.

Kinematic: Not determined.

Solvent content:

Organic solvents: 0.0 %

Solids content: 50.0 %

Other information No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity May intensify fire; oxidizer.

Chemical stability Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored

according to specifications.

Possibility of hazardous reactions

Water reacts violently with alkali metals.

Water reacts with many metals to give hydrogen, often violently. Water is also incompatible with many

reactive organic and inorganic chemicals.

Reacts with reducing agents

Reacts with flammable substances

Conditions to avoid No data available

Incompatible materials:

Flammable substances

Reducing agents

Bases

Organic materials

Metal powders

Hazardous decomposition products:

Nitrogen oxides

Metal oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

Harmful if swallowed.

Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation

of esophagus and stomach.

The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for

components in this product.

LD/LC50 values that are relevant for classification: No data

Skin irritation or corrosion: Causes severe skin burns.

Eye irritation or corrosion: Causes serious eye damage.

Sensitization: No sensitizing effects known.Germ cell mutagenicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains

mutation data for components in this product.

Carcinogenicity:

EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of

carcinogenicity or no data are available.

ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in

terms of its carcinogenicity in humans and/or animals.

Reproductive toxicity: No effects known.

Specific target organ system toxicity - repeated exposure:

May cause damage to the brain through prolonged or repeated exposure. Route of exposure:

Inhalative.

Specific target organ system toxicity - single exposure: No effects known.

Aspiration hazard: No effects known.

Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains

multiple dose toxicity data for this substance.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

The product shows the following dangers according to internally approved calculation methods for

preparations:

Harmful

Corrosive

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity: No data available

Persistence and degradability No data available

Bioaccumulative potential No data available

Mobility in soil No data available

Ecotoxical effects:

Remark: Harmful to aquatic organisms

Additional ecological information:

Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage

systems.

May cause long lasting harmful effects to aquatic life.

Avoid transfer into the environment.

Harmful to aquatic organisms

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

Other adverse effects No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation Consult official regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation: Disposal must be made according to official regulations.

Recommended cleansing agent: Water, if necessary with cleansing agents.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA UN3093

UN proper shipping name

DOT Corrosive liquids, oxidizing, n.o.s. (Manganese nitrate)

IMDG, IATA CORROSIVE LIQUID, OXIDIZING, N.O.S. (MANGANESE NITRATE)

Transport hazard class(es)

DOT

Class 8 Corrosive substances.

Label 8+6.1

Class 8 (CO1) Corrosive substances

Label 8+6.1

IMDG, IATA

Class 8 Corrosive substances.

Label 8+6.1

Packing group

DOT, IMDG, IATA II

Environmental hazards:

Marine pollutant (IMDG): No

Special precautions for user Warning: Corrosive substances

EMS Number: F-A,S-Q

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A

Transport/Additional information:

DOT

Marine Pollutant (DOT): No

UN "Model Regulation": UN3093, Corrosive liquids, oxidizing, n.o.s. (Manganese nitrate), 8 (6.1), II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

GHS label elements, including precautionary statements

Hazard pictograms

GHS03 GHS05 GHS07 GHS08

Signal word Danger

Hazard-determining components of labeling:

Manganese(II) nitrate

Hazard statements

H272 May intensify fire; oxidizer.

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.

H373 May cause damage to the brain through prolonged or repeated exposure. Route of exposure:

Inhalative.

Precautionary statements

P221 Take any precaution to avoid mixing with combustibles.

P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.

P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with

water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P405 Store locked up.P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Domestic Substances List (DSL).

SARA Section 313 (specific toxic chemical listings)

10377-66-9 Manganese(II) nitrate 50.0%

California Proposition 65

Prop 65 - Chemicals known to cause cancer

None of the ingredients are listed.

Prop 65 - Developmental toxicity

None of the ingredients are listed.

Prop 65 - Developmental toxicity, female

None of the ingredients are listed.

Prop 65 - Developmental toxicity, male

None of the ingredients are listed.

Information about limitation of use: For use only by technically qualified individuals.

Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

None of the ingredients are listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the

market and use must be observed.

None of the ingredients is listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

None of the ingredients is listed.

Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.