FL1231 Manganese (III) Fluoride (MnF3) Powder (CAS No. 7783-53-1)

SECTION 1. IDENTIFICATION

Product Name: Manganese(III) Fluoride

CAS #: 7783-53-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)

GHS03 Flame over circle

Ox. Sol. 2

H272 May intensify fire; oxidizer.

GHS06 Skull and crossbones

Acute Tox. 3 H301 Toxic if swallowed.

Acute Tox. 2 H330 Fatal if inhaled.

GHS07

Skin Irrit. 2

H315 Causes skin irritation.

Eye Irrit. 2A H319 Causes serious eye irritation.

STOT SE 3 H335 May cause respiratory irritation.

Hazards not otherwise classified

No information known.

Label elements

GHS label elements

The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)

Hazard pictograms

GHS03 GHS06

Signal word

Danger

Hazard statements

H272 May intensify fire; oxidizer.

H301 Toxic if swallowed.

H330 Fatal if inhaled.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

Precautionary statements

P221

Take any precaution to avoid mixing with combustibles.

P301+P310

IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,

if present and easy to do. Continue rinsing.

P320

Specific treatment is urgent (see on this label).

P405

Store locked up.

P501

Dispose of contents/container in accordance with local/regional/national/international regulations.

WHMIS classification

C - Oxidizing materials

D1A - Very toxic material causing immediate and serious toxic effects

D2B - Toxic material causing other toxic effects

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

Health (acute effects) = 3

Flammability = 3

Physical Hazard = 2

Other hazards

Results of PBT and vPvB assessment

PBT:

Not applicable.

vPvB:

Not applicable.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances

CAS# Description:

7783-53-1 Manganese(III) fluoride

Concentration:≤100%

Identification number(s):

EC number: 232-006-6

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General information

Immediately remove any clothing soiled by the product.

Remove breathing apparatus only after contaminated clothing has been completely removed.

In case of irregular breathing or respiratory arrest provide artificial respiration.

After inhalation

Supply fresh air. If required, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

After skin contact

Immediately wash with water and soap and rinse thoroughly.

Rub in calcium gluconate solution or calcium gluconate gel immediately.

Seek immediate medical advice.

After eye contact

Rinse opened eye for several minutes under running water. Then consult a doctor.

After swallowing

Do not induce vomiting; immediately call for medical help.

Information for doctor

Most important symptoms and effects, both acute and delayed

Causes skin irritation.

Causes serious eye irritation.

Fatal if inhaled.

Toxic if swallowed.

Indication of any immediate medical attention and special treatment needed

No further relevant information available.

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Use carbon dioxide, extinguishing powder or foam. Water may be ineffective but may be used for

cooling exposed containers.

For safety reasons unsuitable extinguishing agents

Halocarbon extinguisher

Special hazards arising from the substance or mixture

This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause

ignition.

If this product is involved in a fire, the following can be released:

Hydrogen fluoride (HF)

Manganese oxides

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear protective equipment. Keep unprotected persons away.Ensure adequate ventilation

Environmental precautions:

Do not allow material to be released to the environment without proper governmental permits.

Methods and material for containment and cleaning up:

Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

Acts as an oxidizing agent on organic materials such as wood, paper and fats

Keep away from combustible material.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

Protective Action Criteria for Chemicals

PAC-1:

Substance is not listed.

PAC-2:

Substance is not listed.

PAC-3:

Substance is not listed.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Handle under dry protective gas.

Keep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.

Open and handle container with care.

Information about protection against explosions and fires:

Substance/product can reduce the ignition temperature of flammable substances.

This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause

ignition.

Conditions for safe storage, including any incompatibilities

Storage

Requirements to be met by storerooms and receptacles:

No special requirements.

Information about storage in one common storage facility:

Store away from flammable substances.

Store away from reducing agents.

Do not store with organic materials.

Store away from metal powders.

Store away from water/moisture.

Further information about storage conditions:

Store under dry inert gas.

This product is hygroscopic.

Keep container tightly sealed.

Store in cool, dry conditions in well sealed containers.

Protect from humidity and water.

Specific end use(s)

No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and having an average

face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have to be

monitored at the workplace.

Additional information:

No data

Exposure controls

Personal protective equipment

General protective and hygienic measures

The usual precautionary measures for handling chemicals should be followed.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Avoid contact with the eyes and skin.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Use self-contained respiratory protective device in emergency situations.

Recommended filter device for short term use:

Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls.

Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only

use equipment tested and approved under appropriate government standards.

Protection of hands:

Impervious gloves

Check protective gloves prior to each use for their proper condition.

The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary

from manufacturer to manufacturer.

Eye protection:

Safety glasses with side shields / NIOSH (US) or EN 166(EU)

Body protection:

Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

General Information

Appearance:

Form: Crystalline

Odor: Not determined

Odor threshold: Not determined.

pH-value: Not applicable.

Change in condition

Melting point/Melting range: Not determined

Boiling point/Boiling range: Not determined

Sublimation temperature / start: Not determined

Flash point: Not applicableFlammability (solid, gaseous)

Contact with combustible material may cause fire.

Ignition temperature: Not determined

Decomposition temperature: Not determined

Auto igniting: Not determined.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:

Lower: Not determined

Upper: Not determined

Vapor pressure: Not applicable.

Density at 20 °C (68 °F): 3.54 g/cm³ (29.541 lbs/gal)

Relative density

Not determined.

Vapor density

Not applicable.

Evaporation rate

Not applicable.

Solubility in / Miscibility with Water: Decomposes

Partition coefficient (n-octanol/water): Not determined.

Viscosity:

dynamic: Not applicable.

kinematic: Not applicable.

Other information

No further relevant information available.

SECTION 10. STABILITY AND REACTIVITY

Reactivity

May intensify fire; oxidizer.

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

Reacts with reducing agents

Reacts with flammable substances

Conditions to avoid

No further relevant information available.

Incompatible materials:

Flammable substances

Reducing agents

Water/moisture

Organic materials

Metal powders

Hazardous decomposition products:

Hydrogen fluoride (HF)

Hydrogen fluoride

Manganese oxides

SECTION 11. TOXICOLOGICAL INFORMATIONInformation on toxicological effects

Acute toxicity:

Fatal if inhaled.

Toxic if swallowed.

The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this

substance.

LD/LC50 values that are relevant for classification:

Oral

LD50 86 mg/kg (mouse)

Inhalative LC50 320 mg/m3 (mouse)

Skin irritation or corrosion:

Irritant to skin and mucous membranes.

Eye irritation or corrosion:

Irritating effect.

Sensitization:

No sensitizing effects known.

Germ cell mutagenicity:

No effects known.

Carcinogenicity:

ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in

terms of its carcinogenicity in humans and/or animals.

Reproductive toxicity:

No effects known.

Specific target organ system toxicity - repeated exposure:

No effects known.

Specific target organ system toxicity - single exposure:

May cause respiratory irritation.

Aspiration hazard:

No effects known.

Subacute to chronic toxicity:

The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for

this substance.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of

carcinogenicity or no data are available.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No further relevant information available.

Persistence and degradability

No further relevant information available.

Bioaccumulative potential

No further relevant information available.

Mobility in soil

No further relevant information available.

Additional ecological information:

General notes:

Do not allow material to be released to the environment without proper governmental permits.

Do not allow undiluted product or large quantities to reach ground water, water course or sewage

system.Avoid transfer into the environment.

Results of PBT and vPvB assessment

PBT:

Not applicable.

vPvB:

Not applicable.

Other adverse effects

No further relevant information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation

Consult state, local or national regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA

UN3087

UN proper shipping name

DOT

Oxidizing solid, toxic, n.o.s. (Manganese(III) fluoride)

ADR

3087 Oxidizing solid, toxic, n.o.s. (Manganese(III) fluoride)

IMDG, IATA

OXIDIZING SOLID, TOXIC, N.O.S. (Manganese(III) fluoride)

Transport hazard class(es)

DOT

Class

5.1 Oxidizing substances

Label

5.1, 6.1

ADR

Class

5.1 (OT2) Oxidizing substances

Label

5.1+6.1

IMDG

Class

5.1 Oxidizing substances

Label

5.1/6.1

IATA

Class

5.1 Oxidizing substances

Label

5.1 (6.1)Packing group

DOT, ADR, IMDG, IATA

II

Environmental hazards:

Not applicable.

Special precautions for user

Warning: Oxidizing substances

EMS Number: F-A,S-Q

Stowage Category

B

Segregation Code

SG38 Stow "separated from" ammonium compounds.

SG49 Stow "separated from" cyanides

SG60 Stow "separated from" peroxides

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable.

Transport/Additional information:

DOT

Marine Pollutant (DOT):

No

UN "Model Regulation":

UN 3087 OXIDIZING SOLID, TOXIC, N.O.S. (MANGANESE(III) FLUORIDE), 5.1(6.1), II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

GHS label elements

The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)

Hazard pictograms

GHS03

GHS06

Signal word

Danger

Hazard statements

H272 May intensify fire; oxidizer.

H301 Toxic if swallowed.

H330 Fatal if inhaled.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

Precautionary statements

P221

Take any precaution to avoid mixing with combustibles.

P301+P310

IF SWALLOWED: Immediately call a POISON CENTER/ doctor.

P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,

if present and easy to do. Continue rinsing.

P320

Specific treatment is urgent (see on this label).

P405

Store locked up.

P501

Dispose of contents/container in accordance with local/regional/national/international regulations.National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).

SARA Section 313 (specific toxic chemical listings)

Substance is not listed.

California Proposition 65

Prop 65 - Chemicals known to cause cancer

Substance is not listed.

Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

For use only by technically qualified individuals.

Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

Substance is not listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.

Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorization for use)

Substance is not listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.