SECTION 1. IDENTIFICATION
Product Name: Niobium(V) Chloride
CAS #: 10026-12-7
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS05 Corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard-determining components of labeling:
niobium pentachloride
Hazard statements
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P231 Handle under inert gas.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin
with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if
present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P422 Store contents under inert gas.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Classification system:
NFPA ratings (scale 0 - 4)
3
0
0
Health = 3
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
4
0
0
Health = 4
Fire = 0
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS # / Substance Name
10026-12-7 niobium pentachloride
Identification number(s)
EC number: 233-059-8
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.Symptoms of poisoning may even occur after several hours; therefore medical observation for at least
48 hours
after the accident.
If inhaled: In case of unconsciousness place patient stably in side position for transportation.
In case of skin contact: Immediately wash with soap and water; rinse thoroughly.
In case of eye contact: Rinse opened eye for several minutes under running water. Consult a
physician.
If swallowed:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture No data available
Advice for firefighters
Protective equipment: No special measures required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Environmental precautions: No special measures required.
Methods and materials for containment and cleanup:
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Precautions for safe handling Thorough dedusting.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Specific end use(s) No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems: No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment: Not required.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be
observed.
Eye protection:
Tightly sealed goggles
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Crystalline
Color: Yellow
Odor: Pungent
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: 204-206 °C (399-403 °F)
Boiling point/Boiling range: 254 °C (489 °F)
Flash point: N/A
Flammability (solid, gas): Product is not flammable.
Ignition temperature:
Decomposition temperature: No data available.
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:Lower: No data available.
Upper: No data available.
Vapor pressure: sublimes hPa
Density at 20 °C (68 °F): 2.75 g/cm
3
(22.949 lbs/gal)
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in / Miscibility with
Water: Insoluble.
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Organic solvents: 0.0 %
Solids content: 100.0 %
Other information No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to
specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No data available
Incompatible materials: No data available
Hazardous decomposition products: No dangerous decomposition products known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
10026-12-7 niobium pentachloride
Oral LD50 1400 mg/kg (rat)
Primary irritant effect:
on the skin: Strong caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization: No sensitizing effects known.
Additional toxicological information:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer)
Substance is not listed.
NTP (National Toxicology Program)
Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration)Substance is not listed.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Additional ecological information: Must not reach bodies of water or drainage ditch undiluted or
unneutralized.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to enter drains,
sewage systems, or other water courses system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA UN3260
UN proper shipping name
DOT Corrosive solid, acidic, inorganic, n.o.s.
IMDG, IATA CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Transport hazard class(es)
DOT
Class 8 Corrosive substances
Label 8
IMDG, IATA
Class 8 Corrosive substances
Label 8
Packing group
DOT, IMDG, IATA II
Environmental hazards:
Marine pollutant: No
Special precautions for user Warning: Corrosive substances
EMS Number: F-A,S-B
Segregation groups Acids
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOTQuantity limitations On passenger aircraft/rail: 15 kg
On cargo aircraft only: 50 kg
IMDG
Limited quantities (LQ) 1 kg
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 500 g
UN "Model Regulation": UN3260, Corrosive solid, acidic, inorganic, n.o.s., 8, II
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
Substance is not listed.
Section 313 (Specific toxic chemical listings):
Substance is not listed.
TSCA (Toxic Substances Control Act):
Substance is listed.
Proposition 65
Chemicals known to cause cancer:
Substance is not listed.
Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
Chemicals known to cause developmental toxicity:
Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
Substance is not listed.
TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard-determining components of labeling:
niobium pentachloride
Hazard statements
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P231 Handle under inert gas.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin
with water/shower.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if
present and easy to do. Continue rinsing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P422 Store contents under inert gas.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
GHS05, GHS07