SECTION 1. IDENTIFICATION
Product Name: Hafnium Chloride
CAS #: 13499-05-3
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Skin corrosion (Category 1B), H314
Serious eye damage (Category 1), H318
For the full text of the H-Statements mentioned in this Section, see Section 16.
GHS Label elements, including precautionary statements
Pictogram
Signal word Danger
Hazard statement(s)
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
Precautionary statement(s)
P260 Do not breathe dust or mist.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately
call a POISON CENTER/doctor.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS - none
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : Cl4Hf
Molecular weight : 320.3 g/mol
CAS-No. : 13499-05-3
EC-No. : 236-826-5
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous
area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a
physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water.
Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Continue rinsing
eyes during transport to hospital.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
water. Consult a physician.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2) and/or
in section 11
Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the substance or mixture
Hydrogen chloride gas, Hafnium oxide
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas.
Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.
SECTION 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid formation of dust and aerosols.Further processing of solid materials may result in the formation
of combu
formation should be taken into consideration before additional processing
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Moisture sensitive. Keep in a dry place.
Specific end use(s)
Apart from the uses mentioned in section 1 no other specific uses are stipulated
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks
and at the end of workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use (EN 143) respirator
cartridges as a backup to engineering controls. If th full-face supplied air respirator. Use respirators
and components tested and approved under appropriate government standards such as NIOSH (US)
or CEN (EU).
Control of environmental exposure
Do not let product enter drains.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance Form: powder
Odour No data available
Odour Threshold No data available
pH No data available
Melting point/freezing point
No data available
Initial boiling point and boiling range
No data available
Flash point Not applicable
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability or explosive limits
No data available
Vapour pressure 1 hPa at 190 °C (374 °F)
Vapour density No data available
Relative density No data available
Water solubility No data available
Partition coefficient: noctanol/water
No data available
Auto-ignition temperature
No data available
Decomposition temperature
No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available
Other safety information
No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data availableConditions to avoid
No data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Hydrogen chloride gas, Hafnium
oxide
Other decomposition products - No data available
In the event of fire: see section 5
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
No data availableHafnium tetrachloride
Inhalation: No data available(Hafnium tetrachloride)
Dermal: No data available(Hafnium tetrachloride)
No data available(Hafnium tetrachloride)
Skin corrosion/irritation
No data available(Hafnium tetrachloride)
Serious eye damage/eye irritation
No data available(Hafnium tetrachloride)
Respiratory or skin sensitisation
No data available(Hafnium tetrachloride)
Germ cell mutagenicity
No data available(Hafnium tetrachloride)
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available(Hafnium tetrachloride)
No data available(Hafnium tetrachloride)
Specific target organ toxicity - single exposure
No data available(Hafnium tetrachloride)
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available(Hafnium tetrachloride)
Additional Information
RTECS: Not available
burning sensation, Cough, wheezing, laryngitis, Shortness of breath, spasm, inflammation and edema
of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema,
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes,and skin., To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.(Hafnium tetrachloride)
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available(Hafnium tetrachloride)
Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material. Dissolve or mix the material with a
combustible solvent and burn in a chem scrubber.
Contaminated packaging
Dispose of as unused product.
SECTION 14. TRANSPORT INFORMATION
DOT (US)
UN number: 3260 Class: 8 Packing group: II
Proper shipping name: Corrosive solid, acidic, inorganic, n.o.s. (Hafnium tetrachloride)
Poison Inhalation Hazard: No
IMDG
UN number: 3260 Class: 8 Packing group: II EMS-No: F-A, S-B
Proper shipping name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Hafnium tetrachloride)
IATA
UN number: 3260 Class: 8 Packing group: II
Proper shipping name: Corrosive solid, acidic, inorganic, n.o.s. (Hafnium tetrachloride)
SECTION 15. REGULATORY INFORMATION
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.SARA 311/312 Hazards
Acute Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Hafnium tetrachloride
CAS-No.
13499-05-3
Revision Date
New Jersey Right To Know Components
Hafnium tetrachloride
CAS-No.
13499-05-3
Revision Date
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth
defects, or any other reproductive harm.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
GHS05