SECTION 1. IDENTIFICATION
Product Name: Molybdenum Nanoparticle Dispersion
CAS #: 7439-98-7
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS02 Flame
Flam. Sol. 2 H228 Flammable solid.
Hazards not otherwise classified
No data available.
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictogram
GHS02
Signal word
Warning
Hazard statements
H228 Flammable solid.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
WHMIS classification
B4 - Flammable solid
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
1
2
1
Health (acute effects) = 1
Flammability = 2
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment:
PBT:
N/A.
vPvB:
N/A.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS No. / Substance Name:
7439-98-7 Molybdenum
Identification number(s):
EC number:
231-107-2
SECTION 4. FIRST AID MEASURES
Description of first aid measures
If inhaled:
Supply fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No information available.
Indication of any immediate medical attention and special treatment needed
No information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing media
Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Molybdenum oxides
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow material to be released to the environment without official permits.
Methods and material for containment and cleanup:
Keep away from ignition sources.
Ensure adequate ventilation.
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure adequate ventilation.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Do not store together with acids.
Further information about storage conditions:Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
7439-98-7 Molybdenum (100.0%)
PEL (USA) Long-term value: 5* 15** mg/m³
as Mo;*soluble compds.,
**insol.compds.:total dust
TLV (USA) Long-term value: 10* 3** mg/m³
as Mo; *inhalable fraction ** respirable fraction
EL (Canada) Long-term value: 3* 10** mg/m³
as Mo; *respirable **inhalable
EV (Canada) Long-term value: 10* 3** 0.5*** mg/m³
metal,insol.compd.:*inh;**resp;sol.compd.:***resp
Additional information:
No data
Exposure controls
Personal protective equipment
Follow typical general protective and industrial hygiene measures for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type N95 (USA) or PE (EN 143) cartridges as a backup to engineering controls.
Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only
use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only
depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
480
Glove thickness
0.11 mm
Eye protection:
Safety glasses
Body protection:
Protective work clothing
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form:
Powder
Color:
gray
Odor:
Odorless
Odor threshold:
No data available.
pH:
N/A.
Melting point/range:
2623 °C (4753 °F)
Boiling point/range:
4639 °C (8382 °F)
Sublimation temperature / start:
No data available.
Flammability (solid, gas):
Highly flammable.
Ignition temperature:
No data available.
Decomposition temperature:
No data available.
Auto igniting:
No data available.
Danger of explosion:
No data available.
Explosion limits:
Lower:
No data available.
Upper:
No data available.
Vapor pressure:
N/A.
Density at 20 °C (68 °F):
10.22 g/cm³ (85.286 lbs/gal)
Relative density
No data available.
Vapor density
N/A.
Evaporation rate
N/A.
Solubility in / Miscibility with
Water:
No data available.
Partition coefficient (n-octanol/water):
No data available.
Viscosity:
Dynamic:
N/A.Kinematic:
N/A.
Other information
No information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No information available.
Incompatible materials:
Acids
Oxidizing agents
Hazardous decomposition products:
Molybdenum oxides
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this
substance.
LD/LC50 values that are relevant for classification:
No data
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for this
substance.
Carcinogenicity:
No classification data on carcinogenic properties of this material is available from the EPA, IARC,
NTP, OSHA or ACGIH.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances
(RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure:
N/A
Specific target organ system toxicity - single exposure:
N/A
Aspiration hazard:N/A
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for
this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No information available.
Persistence and degradability:
No information available.
Bioaccumulative potential:
No information available.
Mobility in soil:
No information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without official permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage
system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment:
PBT:
N/A.
vPvB:
N/A.
Other adverse effects
No further relevant information available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation:
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA
UN308
SECTION 15. REGULATORY INFORMATION
UN proper shipping name
DOT
Metal powders, flammable, n.o.s. (Molybdenum powder)
IMDG, IATA
METAL POWDER, FLAMMABLE, N.O.S. (Molybdenum powder)
Transport hazard class(es)
DOT
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Class
4.1 (F3) Flammable solids, self-reactive substances and solid desensitised explosives
Label
4.1
IMDG, IATA
Class
4.1 Flammable solids, self-reactive substances and solid desensitised explosives.
Label
4.1
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
N/A.
Special precautions for user
Warning: Flammable solids, self-reactive substances and solid desensitised explosives
EMS Number:
F-G,S-G
Segregation groups
Heavy metals and their salts (including their organometallic compounds), powdered metals
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3089, Metal powders, flammable, n.o.s. (Molybdenum powder), 4.1, III
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS07
Eye Irrit. 2
H319 Causes serious eye irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
Hazards not otherwise classified
No information known.Label elements
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS02 GHS07
Signal word
Danger
Hazard statements
H225 Highly flammable liquid and vapor.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
B2 - Flammable liquid
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 3
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Substances
CAS# Description:
7439-98-7 Molybdenum
Identification number(s):
EC number: 231-107-267-63-0 2-Propanol
Identification number(s):
EC number: 200-661-7
Index number: 603-117-00-0
SECTION 4. FIRST AID MEASURES
Description of first aid measures
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents
Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol
resistant foam.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Carbon monoxide and carbon dioxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
Do not allow product to reach sewage system or any water course.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Prevention of secondary hazards:Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires:
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
Keep ignition sources away.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from oxidizing agents.
Store away from halogens.
Store away from acid anhydrides.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s)
No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with multi-purpose combination (US) or type ABEK (EN 14387) as a backup to
engineering controls. Risk assessment should be performed to determine if air-purifying respirators
are appropriate. Only use equipment tested and approved under appropriate government standards
such as NIOSH (USA) or CEN (EU).Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary
from manufacturer to manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
480
Glove thickness
0.4 mm
Eye protection:
Safety glasses
Body protection:
Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form: Liquid
Odor: Alcohol-like
Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Melting range: Not determined.
Boiling point/Boiling range: Not determined.
Sublimation temperature / start: Not determined
Flash point: Not determined.
Flammability (solid, gaseous)
Not determined.
Ignition temperature: Not determined.
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures is
possible.
Relative density
Not determined.
Vapor density
Not determined.
Evaporation rate
Not determined.
Viscosity:
dynamic at 20 °C (68 °F): Not determined.
kinematic: Not determined.
Other information
No further relevant information available.
SECTION 10. STABILITY AND REACTIVITYReactivity
No information known.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No further relevant information available.
Incompatible materials:
Acids
Oxidizing agents
Halogens
Acid anhydrides
Hazardous decomposition products:
Carbon monoxide and carbon dioxide
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this
substance.
LD/LC50 values that are relevant for classification:
Oral
LD50
5045 mg/kg (rat)
Dermal
LD50
12800 mg/kg (rabbit)
Inhalative LC50/8H 12560 ppm/8H (rat)
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
Causes serious eye irritation.
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for this
substance.
Carcinogenicity:
IARC-3: Not classifiable as to carcinogenicity to humans.
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in
terms of its carcinogenicity in humans and/or animals.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this
substance.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
May cause drowsiness or dizziness.
May cause respiratory irritation.Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for
this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow undiluted product or large quantities to reach ground water, water course or sewage
system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Recommended cleansing agent:
Water, if necessary with cleansing agents.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA
UN1219
UN proper shipping name
DOTIsopropanol (Isopropyl alcohol)
IMDG, IATA
ISOPROPANOL (ISOPROPYL ALCOHOL)
Transport hazard class(es)
DOT
Class
3 Flammable liquids.
Label
3
Class
3 (F1) Flammable liquids
Label
3
IMDG, IATA
Class
3 Flammable liquids.
Label
3
Packing group
DOT, IMDG, IATA
II
Environmental hazards:
Not applicable.
Special precautions for user
Warning: Flammable liquids
EMS Number: F-E,S-D
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN1219, Isopropanol (Isopropyl alcohol), 3, II
SECTION 15. REGULATORY INFORMATION
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
67-63-0 2-Propanol
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
