NN0237 Nano Silicon Powder (Si) (CAS No.7440-21-3)

SECTION 1. IDENTIFICATION

Product Name: Silicon Nanoparticles

CAS #: 7440-21-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Flammable solids (Category 2), H228

For the full text of the H-Statements mentioned in this Section, see Section 16.

Pictogram

Signal word

Warning

Hazard statement(s)

H228

Flammable solid.

Precautionary statement(s)

P210

Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

P240

Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ ventilating/ lighting/ equipment.

P280

Wear protective gloves/ protective clothing/ eye protection/ face protection.

P370 + P378

In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.

Hazards not otherwise classified (HNOC) or not covered by GHS-none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Formula: Si

Molecular Weight: 28.09 g/mol

CAS-No.: 7440-21-3

EC-No.: 231-130-8

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous

area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a

physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with

water. Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2) and/or

in section 11.

Indication of any immediate medical attention and special treatment needed

no data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

silicon oxides

Advice for firefighters

Wear self contained breathing apparatus for fire fighting if necessary.

Further information

Use water spray to cool unopened containers.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure

adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Avoid

breathing dust. For personal protection see section 8.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Methods and materials for containment and cleaning up

Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner

or by wet-brushing and place in container for disposal according to local regulations (see section 13).

Keep in suitable, closed containers for disposal. Contain spillage, pick up with an electrically protected

vacuum cleaner or by wet-brushing and transfer to a container for disposal according to local

regulations (see section 13)

Reference to other sections

For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin andeyes. Avoid formation of dust and aerosols.Further processing of solid

materials may result in the formation of combustible dusts. The potential for combustible dust

formation should be taken into consideration before additional processing occurs.

Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of

ignition -No smoking.Take measures to prevent the build up of electrostatic charge.

For precautions see section 2.

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place.

Over time, pressure may increase causing containers to burst Moisture sensitive. Store under

nitrogen. Keep in a dry place.

Specific end use(s)

Apart from the uses mentioned in section 1 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks

and at the end of workday.

Personal protective equipment

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye protecti

on tested and approved under appropriate government standards such as NIOSH (US) or EN

166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique

(without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

Body Protectionimpervious clothing, Flame retardant antistatic protective clothing, The type of protective equipment

must be selected according to the concentration and amount of the dangerous substance at the

specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle

respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering

controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use

respirators and components tested and approved under appropriate government standards such as

NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Form: powder

Odor

odourless

Odor Threshold

no data available

pH

no data available

Melting point/freezing point

Melting point/range: 1,410 °C (2,570 °F) - lit.

Initial boiling point and boiling range

2,355 °C (4,271 °F) - lit.

Flash point

no data available

Evaporation rate

no data available

Flammability (solid, gas)

The substance or mixture is a flammable solid with the category 2.

Upper/lower flammability or explosive limits

no data available

Vapor pressure

no data available

Vapor density

no data available

Relative density

2.33 g/mL at 25 °C (77 °F)

Water solubility

insoluble

Partition coefficient: n-octanol/water

no data available

Auto-ignition temperature

> 400 °C (> 752 °F)

Decomposition temperature

no data available

Viscosity

no data available

Explosive properties

no data availableOxidizing properties

no data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

no data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

no data available

Conditions to avoid

Heat, flames and sparks. Extremes of temperature and direct sunlight.

Incompatible materials

Strong oxidizing agents, Alkali carbonates, Calcium, cobalt difluoride, manganese trifluoride

Hazardous decomposition products

Other decomposition products - no data available

In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

LD50 Oral - rat - 3,160 mg/kg

Inhalation: no data available

Dermal: no data available

no data available

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

Eyes - rabbit

Result: Mild eye irritation - 24 h

(Draize Test)

Respiratory or skin sensitisation

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

IARC:

No component of this product present at levels greater than or equal to 0.1% is identified as probable,

possible or confirmed human carcinogen by IARC.

ACGIH:

No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by ACGIH.

NTP:

No component of this product present at levels greater than or equal to 0.1% is identified as a known

or anticipated carcinogen by NTP.

OSHA:

No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by OSHA.

Reproductive toxicityno data available

no data available

Specific target organ toxicity - single exposure

no data available

Specific target organ toxicity - repeated exposure

no data available

Aspiration hazard

no data available

Additional Information

RTECS: VW0400000

To the best of our knowledge, the chemical, physical, and toxicological properties have not been

thoroughly investigated.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

no data available

Persistence and degradability:

no data available

Bioaccumulative potential:

no data available

Mobility in soil:

no data available

Results of PBT and vPvB assessment:

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in

igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed

disposal company.

Contaminated packaging

Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)

UN number: 1346

Class: 4.1

Packing group: III

Proper shipping name: Silicon powder, amorphous

Reportable Quantity (RQ):

Marine pollutant: No

Poison Inhalation Hazard: No

IMDG

UN number: 1346Class: 4.1

Packing group: III

EMS-No: F-A, S-G

Proper shipping name: SILICON POWDER, AMORPHOUS

Marine pollutant: No

IATA

UN number: 1346

Class: 4.1

Packing group: III

Proper shipping name: Silicon powder, amorphous

SECTION 15. REGULATORY INFORMATION

SARA 302 Components

SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 Components

SARA 313: This material does not contain any chemical components with known CAS numbers that

exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards

Fire Hazard

Massachusetts/Pennsylvania/New Jersey Right To Know Components

Silicon

CAS-No.

7440-21-3

Revision Date

2007-03-01

California Prop. 65 Components

This product does not contain any chemicals known to State of California to cause cancer, birth

defects, or any other reproductive harm.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.