VD0706 Lead Titanate (PbTiO3) Evaporation Materials

SECTION 1. IDENTIFICATION

Product Name: Lead(II) Titanate

CAS #: 12060-00-3

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Acute toxicity, Oral (Category 4), H302

Acute toxicity, Inhalation (Category 4), H332

Carcinogenicity (Category 1B), H350

Reproductive toxicity (Category 1A), H360

Specific target organ toxicity - repeated exposure (Category 2), H373

Short-term (acute) aquatic hazard (Category 1), H400

Long-term (chronic) aquatic hazard (Category 1), H410

For the full text of the H-Statements mentioned in this Section, see Section 16.

GHS Label elements, including precautionary statements

Pictogram

Signal word Danger

Hazard statement(s)

H302 + H332 Harmful if swallowed or if inhaled.

H350 May cause cancer.H360 May damage fertility or the unborn child.

H373 May cause damage to organs through prolonged or repeated

exposure.

H410 Very toxic to aquatic life with long lasting effects.

Precautionary statement(s)

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and

understood.

P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.

P264 Wash skin thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye protection/ face

protection.

P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel

unwell. Rinse mouth.

P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable

for breathing. Call a POISON CENTER/doctor if you feel unwell.

P308 + P313 IF exposed or concerned: Get medical advice/ attention.

P391 Collect spillage.

P405 Store locked up.

P501 Dispose of contents/ container to an approved waste disposal

plant.

Hazards not otherwise classified (HNOC) or not covered by GHS - none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Formula : O3PbTi

Molecular weight : 303.07 g/mol

CAS-No. : 12060-00-3

EC-No. : 235-038-9

Index-No. : 082-001-00-6

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of

dangerous area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration.

Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult

a physician.

Most important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section

2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Titanium/titanium oxides, Lead oxides

Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information

No data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist

or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing

dust.

For personal protection see section 8.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Discharge into the environment must be avoided.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in

suitable, closed containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.Further processing

of solid materials may result in the formation of combustible dusts. The potential for

combustible dust formation should be taken into consideration before additional processing

occurs.

Provide appropriate exhaust ventilation at places where dust is formed.

For precautions see section 2.

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place.

Keep in a dry place.

Storage class (TRGS 510): 6.1D: Non-combustible, acute toxic Cat.3 / toxic hazardous

materials or hazardous materials causing chronic effects

Specific end use(s)

Apart from the uses mentioned in section 1 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands

before breaks and at the end of workday.

Personal protective equipment

Eye/face protection

Safety glasses with side-shields conforming to EN166 Use equipment for eye

protection tested and approved under appropriate government standards such as

NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove

removal technique (without touching glove's outer surface) to avoid skin contact

with this product. Dispose of contaminated gloves after use in accordance with

applicable laws and good laboratory practices. Wash and dry hands.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must

be selected according to the concentration and amount of the dangerous substance

at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a fullface

particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as

a backup to engineering controls. If the respirator is the sole means of protection,

use a full-face supplied air respirator. Use respirators and components tested and

approved under appropriate government standards such as NIOSH (US) or CEN

(EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

Discharge into the environment must be avoided.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

a) Appearance Form: powder

Colour: beige

b) Odour No data available

c) Odour Threshold No data available

d) pH No data available

e) Melting point/freezing point

Melting point/freezing point: ca.1,756 °C (ca.3,193 °F) - OECD

Test Guideline 102

f) Initial boiling point and boiling range No data available

g) Flash point ()Not applicable

h) Evaporation rate No data available

i) Flammability (solid, gas) No data available

j) Upper/lower flammability or explosive limits No data available

k) Vapour pressure No data available

l) Vapour density No data available

m) Relative density 7.52 g/cm3 at 25 °C (77 °F)

n) Water solubility 0.00008 g/l at 25 °C (77 °F) - insoluble

o) Partition coefficient: n-octanol/water No data availablep) Auto-ignition temperature No data available

q) Decomposition temperature No data available

r) Viscosity No data available

s) Explosive properties No data available

t) Oxidizing properties No data available

Other safety information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

No data available

Conditions to avoid

No data available

Incompatible materials

Strong oxidizing agents

Hazardous decomposition products

Hazardous decomposition products formed under fire conditions. - Titanium/titanium

oxides, Lead oxides

Other decomposition products - No data available

In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - > 12,000 mg/kg

Inhalation: No data available

Dermal: No data available

No data available

Skin corrosion/irritation

No data available

Serious eye damage/eye irritation

No data available

Respiratory or skin sensitisation

No data available

Germ cell mutagenicity

No data available

Carcinogenicity

IARC: 2A - Group 2A: Probably carcinogenic to humans (Lead titanium trioxide)

NTP: No component of this product present at levels greater than or equal to 0.1% is

identified as a known or anticipated carcinogen by NTP.

OSHA: No component of this product present at levels greater than or equal to 0.1% is

on OSHA’s list of regulated carcinogens.

Reproductive toxicity

Presumed human reproductive toxicant

Known human reproductive toxicantSpecific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard

No data available

Additional Information

RTECS: Not available

Lead salts have been reported to cross the placenta and to induce embryo- and fetomortality.

They also have teratogenic effect in some animal species. No teratogenic effects

have been reported with exposure to organometallic lead compounds. Adverse effects of

lead on human reproduction, embryonic and fetal development, and postnatal (e.g.,

mental) development have been reported. Excessive exposure can affect blood, nervous,

and digestive systems. The synthesis of hemoglobin is inhibited and results in anemia. If

left untreated, neuromuscular dysfunction, possible paralysis, and encephalopathy can

result. Additional symptoms of overexposure include: joint and muscle pain, weakness of

the extensor muscles (frequently the hand and wrist), headache, dizziness, abdominal pain,

diarrhea, constipation, nausea, vomiting, blue line on the gums, insomnia, and metallic

taste. High body levels produce increased cerebrospinal pressure, brain damage, and

stupor leading to coma and often death.

Stomach - Irregularities - Based on Human Evidence

Stomach - Irregularities - Based on Human Evidence

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not

conducted

Other adverse effects

Very toxic to aquatic life with long lasting effects.

An environmental hazard cannot be excluded in the event of unprofessional handling or

disposal.

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a

licensed professional waste disposal service to dispose of this material. Dissolve or mix

the material with a combustible solvent and burn in a chemical incinerator equipped with

an afterburner and scrubber.

Contaminated packagingDispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)

Not dangerous goods

IMDG

UN number: 3077 Class: 9 Packing group: III EMS-No: F-A, S-F

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Lead

titanium trioxide)

Marine pollutant : yes

IATA

UN number: 3077 Class: 9 Packing group: III

Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (Lead titanium

trioxide)

Further information

EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and

combination packagings containing inner packagings with Dangerous Goods > 5L for liquids

or > 5kg for solids.

SECTION 15. REGULATORY INFORMATION

SARA 302 Components

No chemicals in this material are subject to the reporting requirements of SARA Title III,

Section 302.

SARA 313 Components

This material does not contain any chemical components with known CAS numbers that

exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section

313.

SARA 311/312 Hazards

Acute Health Hazard, Chronic Health Hazard

Massachusetts Right To Know Components

Lead titanium trioxide

CAS-No.

12060-00-3

Revision Date

1993-04-24

No components are subject to the Massachusetts Right to Know Act.

Pennsylvania Right To Know Components

Lead titanium trioxide CAS-No.

12060-00-3

Revision Date

1993-04-24

Lead titanium trioxide CAS-No.

12060-00-3

Revision Date

1993-04-24

New Jersey Right To Know Components

Lead titanium trioxide CAS-No.

12060-00-3

Revision Date1993-04-24

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.