FL1980 Praseodymium (III) Fluoride (PrF3) Powder (CAS No. 13709-46-1)

SECTION 1. IDENTIFICATION

Product Name: Praseodymium Fluoride

CAS #: 13709-46-1

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2A H319 Causes serious eye irritation.

STOT SE 3 H335 May cause respiratory irritation.

GHS label elements

The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

Signal word Warning

Hazard-determining components of labeling:

praseodymium trifluoride

Hazard statements

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H335 May cause respiratory irritation.

Precautionary statementsP231 Handle under inert gas.

P262 Do not get in eyes, on skin, or on clothing.

P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,

if present

and easy to do. Continue rinsing.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P422 Store contents under inert gas.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

Classification system:

NFPA ratings (scale 0 - 4)

1

0

0

Health = 1

Fire = 0

Reactivity = 0

HMIS-ratings (scale 0 - 4)

HEALTH

FIRE

REACTIVITY

1

0

0

Health = 1

Fire = 0

Reactivity = 0

Other hazards

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS No. / Substance Name:

13709-46-1 Praseodymium(III) fluoride

Identification number(s):

EC number:

237-254-9

SECTION 4. FIRST AID MEASURES

Description of first aid measures

If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:Rinse opened eye for several minutes under

running water. Consult a physician.

If swallowed:

Seek medical treatment.

Information for doctor

Most important symptoms and effects, both acute and delayed

No data available

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol

resistant foam.

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Hydrogen fluoride (HF)

Metal oxide fume

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. K

eep unprotected persons away.

Ensure adequate ventilation

Environmental precautions:

Do not allow material to be released to the environment without official permits.

Methods and materials for containment and cleanup:

Dispose of contaminated material

as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

No special measures required.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handling

Handle under dry protective gas.

Keep container tightly sealed.Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.

Information about protection against explosions and fires:

No data available

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles:

No special requirements.

Information about storage in one common storage facility:

Store away from water/moisture.

Do not store together with acids.

Store away from reducing agents.

Further information about storage conditions:

Store under dry inert gas.

This product is hygroscopic.

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Protect from humidity and water.

Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and having an average

face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

13709-46-1 Praseodymium(III) fluoride, anhydrous (100.0%)

PEL (USA)

Long-term value: 2.5 mg/m

3

as F

REL (USA)

Long-term value: 2.5 mg/m

3

as F

TLV (USA)

Long-term value: 2.5 mg/m

3

as F, BEI

EL (Canada) Long-term value: 2.5 mg/m

3

as F

Ingredients with biological limit values:

13709-46-1 Praseodymium(III) fluoride, anhydrous (100.0%)

BEI (USA) 2 mg/L

Medium: urine

Time: prior to shift

Parameter: Fluoride (background, nonspecific)

3 mg/L

Medium: urine

Time: end of shift

Parameter: Fluoride (background, nonspecific)

Additional information:

No data

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.Wash hands before breaks and at the end of work.

Avoid contact with the eyes and skin.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Use suitable respirator when high concentrations are present.

Protection of hands:

Impervious gloves

Inspect gloves prior to use.

The selection of suitable gloves not only

depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.

Penetration time of glove material (in minutes)

No data available

Eye protection:

Safety glasses

Body protection:

Protective work clothing

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form:

Various forms (powder/flake/crystalline/beads, etc.)

Color:

Green

Odor:

Odorless

Odor threshold:

No data available.

pH:

N/A

Melting point/Melting range:

1395 °C (2543 °F)

Boiling point/Boiling range:

No data available

Sublimation temperature / start:

No data available

Flammability (solid, gas)

No data available.

Ignition temperature:

No data available

Decomposition temperature:

No data available

Autoignition:

No data available.

Danger of explosion:

No data available.

Explosion limits:

Lower:

No data available

Upper:

No data available

Vapor pressure:N/A

Density at 20 °C (68 °F):

6.2 g/cm

3

(51.739 lbs/gal)

Relative density

No data available.

Vapor density

N/A

Evaporation rate

N/A

Solubility in / Miscibility with

Water:

Insoluble

Partition coefficient (n-octanol/water):

No data available.

Viscosity:

Dynamic:

N/A

Kinematic:

N/A

Other information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and

stored according to specifications.

Possibility of hazardous reactions

No dangerous reactions known

Conditions to avoid

No data available

Incompatible materials:

Acids

Water/moisture

Reducing agents

Hazardous decomposition products:

Hydrogen fluoride

Metal oxide fume

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity:

Harmful in contact with skin.

Harmful if swallowed.

Toxic if inhaled.

Danger through skin absorption.LD/LC50 values that are relevant for classification:

No data

Skin irritation or corrosion: Causes skin irritation.

Eye irritation or corrosion: Causes serious eye irritation

Sensitization: No sensitizing effects known.

Germ cell mutagenicity: No effects known.

Carcinogenicity:

ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in

terms of its carcinogenicity in humans and/or animals.

Reproductive toxicity: No effects known.

Specific target organ system toxicity - repeated exposure: No effects known.

Specific target organ system toxicity - single exposure: May cause respiratory irritation.

Aspiration hazard: No effects known.

Subacute to chronic toxicity: No effects known.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Additional ecological information:

Do not allow material to be released to the environment without official permits.

Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage

systems.

Avoid transfer into the environment.

Results of PBT and vPvB assessment

PBT:

N/A

vPvB:

N/A

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation

Consult official regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number

DOT, IMDG, IATA

UN3288

UN proper shipping name

DOT

Toxic solid, inorganic, n.o.s. (Praseodymium(III) fluoride, anhydrous)

IMDG, IATA

TOXIC SOLID, INORGANIC, N.O.S. (Praseodymium(III) fluoride, anhydrous)

Transport hazard class(es)

DOT

Class

6.1 Toxic substances.

Label

6.1

Class

6.1 (T5) Toxic substances

Label

6.1

IMDG, IATA

Class

6.1 Toxic substances.

Label

6.1

Packing group

DOT, IMDG, IATA

III

Environmental hazards:

N/A

Special precautions for user

Warning: Toxic substances

EMS Number:

F-A,S-A

Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

N/A

Transport/Additional information:

DOT

Marine Pollutant (DOT):

No

UN "Model Regulation":

UN3288, Toxic solid, inorganic, n.o.s. (Praseodymium(III) fluoride, anhydrous), 6.1, III

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

GHS label elements

The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)

Hazard pictograms

GHS06

Signal wordDanger

Hazard statements

H302+H312 Harmful if swallowed or in contact with skin.

H331

Toxic if inhaled.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H335

May cause respiratory irritation.

Precautionary statements

P261

Avoid breathing dust/fume/gas/mist/vapors/spray.

P280

Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

P304+P340

IF INHALED: Remove person to

fresh air and keep comfortable for breathing.

P405

Store locked up.

P501

Dispose of contents/container in accordance with local/regional/national/international regulations.

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).

SARA Section 313 (specific toxic chemical listings)

Substance is not listed.

California Proposition 65

Prop 65 - Chemicals known to cause cancer

Substance is not listed.

Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

For use only by technically qualified individuals.

Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

Substance is not listed.

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.

Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

Substance is not listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.