SECTION 1. IDENTIFICATION
Product Name: Cobalt(II) Sulfate Heptahydrate
CAS #: 10026-24-1
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS08 Health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1A H350 May cause cancer.
Repr. 1A H360 May damage fertility or the unborn child.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
T; Toxic
R49-60: May cause cancer by inhalation. May impair fertility.
Xn; Harmful
R22-68: Harmful if swallowed. Possible risk of irreversible effects.
Xn; Sensitizing
R42/43: May cause sensitization by inhalation and skin contact.
N; Dangerous for the environment
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.Information concerning particular hazards for human and environment:
N/A
Hazards not otherwise classified
No data available
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms
GHS07
GHS08
Signal word
Danger
Hazard statements
H302 Harmful if swallowed.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
Precautionary statements
P284 In case of inadequate ventilation wear respiratory protection.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor/...
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/
national/international regulations.
WHMIS classification
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
2
0
1
Health (acute effects) = 2
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS No. / Substance Name:
10026-24-1 Cobalt(II) sulfate heptahydrate
Identification number(s):
EC number:
233-334-2
Index number:
027-005-00-0
SECTION 4. FIRST AID MEASURES
Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Sulfur oxides (SOx)
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:Do not allow product to enter drains, sewage systems, or other water courses.
Do not allow material to penetrate the ground or soil.
Methods and materials for containment and cleanup:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
None.
Additional Occupational Exposure Limit Values for related materials or possible hazards during
processing:
10124-43-3 cobalt sulphate
PEL (USA) Long-term value: 0.1* mg/m
3
as Co; *for metal dust and fume
REL (USA) Long-term value: 0.05 mg/m
3
as Co; metal dust & fume
TLV (USA) Long-term value: 0.02 mg/m
3
as Co, BEIAdditional information:
No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type N95 (USA) or PE (EN 143) cartridges as a backup to engineering controls.
Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only
use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by
manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes)
No data available
Eye protection:
Safety glasses
Body protection:
Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Crystalline
Color: Dark red
Odor: Odorless
Odor threshold: No data available.
pH (100 g/l) at 20 °C (68 °F): 4
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flammability (solid, gas)
No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): 2.03 g/cm
3
(16.94 lbs/gal)Relative density
No data available.
Vapor density
N/A
Evaporation rate
N/A
Solubility in / Miscibility with Water at 20 °C (68 °F): 362 g/l
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents
Conditions to avoid
No data available
Incompatible materials:
Oxidizing agents
Hazardous decomposition products:
Sulfur oxides (SOx)
Metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
Harmful if swallowed.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this
substance.
LD/LC50 values that are relevant for classification:
Oral LD50 582 mg/kg (rat)
Skin irritation or corrosion:
May cause irritation
Eye irritation or corrosion:
May cause irritation
Sensitization:
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Germ cell mutagenicity:
Suspected of causing genetic defects.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for thissubstance.
Carcinogenicity:
May cause cancer.
IARC-2B: Possibly carcinogenic to humans: limited evidence in humans in the absence of
sufficient evidence in experimental animals.
NTP-R: Reasonably anticipated to be a carcinogen: limited evidence from studies in humans or
sufficient evidence from studies in experimental animals.
ACGIH A3: Animal carcinogen: Agent is carcinogenic in experimental animals at a relatively high dose,
by route(s) of administration, at site(s), of histologic type(s),or by mechanism(s) not considered
relevant to worker exposure. Available epidemologic studies do not confirm an increased risk of
cancer in exposed humans.
Available evidence suggests that the agent is not likely to cause cancer in humans except under
uncommon or unlikely routes or levels of exposure.
Reproductive toxicity:
May damage fertility or the unborn child.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this
substance.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
No effects known.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity
data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Ecotoxical effects:
Remark:
Very toxic for aquatic organisms
Additional ecological information:
Do not allow product to reach groundwater, water courses, or sewage systems.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Very toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT:
N/AvPvB:
N/A
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA
UN3077
UN proper shipping name
DOT
Environmentally hazardous substances, solid, n.o.s. (Cobalt(II) sulfate heptahydrate)
IMDG, IATA
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Cobalt(II) sulfate heptahydrate)
Transport hazard class(es)
DOT, IMDG
Class
9 Miscellaneous dangerous substances and articles.
Label
9
Class
9 (M7) Miscellaneous dangerous substances and articles
Label
9
IATA
Class
9 Miscellaneous dangerous substances and articles.
Label
9
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
Special marking (ADR):
Symbol (fish and tree)
Special marking (IATA):
Symbol (fish and tree)
Special precautions for user
Warning: Miscellaneous dangerous substances and articles
EMS Number: F-A,S-F
Transport in bulk according to Annex II of MARPOL73/78 and the IBC CodeN/A
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN3077, Environmentally hazardous substances, solid, n.o.s. (Cobalt(II) sulfate heptahydrate), 9, III
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
10026-24-1 Cobalt(II) sulfate heptahydrate
California Proposition 65
Prop 65 - Chemicals known to cause cancer
10026-24-1 Cobalt(II) sulfate heptahydrate
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
This substance is included in the Candidate List of Substances of Very High Concern (
SVHC) according to Regulation (EC) No. 1907/2006 (REACH).
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
