SECTION 1. IDENTIFICATION
Product Name: Cadmium Oxide
CAS #: 1306-19-0
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS06 Skull and crossbones
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1B H350 May cause cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.
Hazards not otherwise classified
No data available
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms
GHS06 GHS08Signal word: Danger
Hazard statements
H330 Fatal if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P284 Wear respiratory protection.
P281 Use personal protective equipment as required.
P320 Specific treatment is urgent (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
WHMIS classification
D1A - Very toxic material causing immediate and serious toxic effects
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
HEALTH
FIRE
REACTIVITY
3
0
1
Health (acute effects) = 3
Flammability = 0
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS No. / Substance Name:
1306-19-0 Cadmium oxide
Identification number(s):
EC number: 215-146-2
Index number: 048-002-00-0
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents
Product is not flammable. Use fire-fighting measures that suit the surrounding fire.
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Cadmium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions:
Do not allow product to enter drains, sewage systems, or other water courses.
Methods and materials for containment and cleanup:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handlingKeep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
The product is not flammable
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from magnesium/magnesium alloys
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s)
No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
1306-19-0 Cadmium oxide (100.0%)
PEL (USA) Long-term value: 0.005 mg/m
3
as Cd; see 29 CFR 1910.1027
REL (USA) See Pocket Guide App. A
TLV (USA) Long-term value: 0.01 0.002* mg/m
3
as Cd; *respirable fraction; BEI
EL (Canada) Long-term value: 0.01 mg/m
3
as Cd; ACIGH A1, IARC 1
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use self-contained respiratory protective device in emergency situations.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls.
Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only
use equipment tested and approved under appropriate government standards.
Protection of hands: Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by
manufacturer.
Material of gloves
Nitrile rubber, NBR
Penetration time of glove material (in minutes): No data available
Eye protection: Safety glassesBody protection: Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Powder or solid in various forms
Color: Red-brown
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: 1430 °C (2606 °F)
Boiling point/Boiling range: No data available
Sublimation temperature / start: 1559 °C (2838 °F)
Flammability (solid, gas): No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): 8.15 g/cm
3
(68.012 lbs/gal)
Relative density: No data available.
Vapor density: N/A
Evaporation rate: N/A
Solubility in Water (H
2
O): Insoluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information
No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No data available
Incompatible materials:
Magnesium/magnesium alloys
Hazardous decomposition products:
Cadmium oxide
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity: Fatal if inhaled.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this
substance.
LD/LC50 values that are relevant for classification:
Oral LD50 72 mg/kg (rat)
Inhalative LC50/1H 45 mg/m3/1H (rat)
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: Suspected of causing genetic defects.
Carcinogenicity: May cause cancer.
IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity.
EPA-B1: Probable human carcinogen, limited evidence of carcinogenicity from epidemiologic studies.
Carcinogen as defined by OSHA.
ACGIH A2: Suspected human carcinogen: Agent is carcinogenic in experimental animals at dose
levels, by route(s) of administration, at site(s), of histologic type(s), or by mechanism(s) considered
relevant to worker exposure. Available epidemiologic studies are conflicting or insufficient to confirm
an increased risk of cancer in exposed humans.
NTP-K: Known to be carcinogenic: sufficient evidence from human studies.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or
carcinogenic and/or neoplastic data for this substance.
Reproductive toxicity:
Suspected of damaging fertility or the unborn child.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this
substance.
Specific target organ system toxicity - repeated exposure:
Causes damage to organs through prolonged or repeated exposure.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for
this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
Carcinogenic categories
OSHA-Ca (Occupational Safety & Health Administration)
Substance is listed.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soilNo data available
Ecotoxical effects:
Remark:
Very toxic for aquatic organisms
Additional ecological information:
Do not allow product to reach groundwater, water courses, or sewage systems, even in small
quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Very toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
DOT (US)
UN number: 2570
Class: 6.1
Packing group: I
Proper shipping name: Cadmium compounds (Cadmium oxide non-pyrophoric)
Reportable Quantity (RQ):
Poison Inhalation Hazard: No
IMDG
UN number: 2570
Class: 6.1
Packing group: I
EMS-No: F-A, S-A
Proper shipping name: CADMIUM COMPOUND (Cadmium oxide non-pyrophoric)
IATA
UN number: 2570
Class: 6.1
Packing group: I
Proper shipping name: Cadmium compound (Cadmium oxide non-pyrophoric)
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
1306-19-0 Cadmium oxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer
1306-19-0 Cadmium oxide
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the
authorities in certain cases.
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
This substance is included in the Candidate List of Substances of Very High Concern (SVHC)
according to Regulation (EC) No. 1907/2006 (REACH).
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
