SECTION 1. IDENTIFICATION
Product Name: Cobalt(II) Bromide Hydrate
CAS #: 85017-77-2
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification
Classification under 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Acute oral toxicity Category 4
Acute dermal toxicity Category 4
Acute Inhalation Toxicity - Dusts and Mists Category 4
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.
Label Elements
Signal Word: Warning
Hazard Statements
H335 - May cause respiratory irritation
H351 - Suspected of causing cancer
H319 - Causes serious eye irritation
H315 - Causes skin irritationH410 - Very toxic to aquatic life with long lasting effects
H302 - Harmful if swallowed
Precautionary Statements
P281 - Use personal protective equipment as required
P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray
P273 - Avoid release to the environment
P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P280 - Wear protective gloves/ protective clothing/ eye protection/ face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and
easy to do. Continue rinsing
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component / CAS-No / Weight %
Cobalt(II) bromide hydrate / 85017-77-2 / 100
SECTION 4. FIRST AID MEASURES
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical
attention.
Skin Contact
Wash off immediately with plenty of water for at least 15 minutes. Get medical attention.
Inhalation
Remove to fresh air. Get medical attention. If not breathing, give artificial respiration.
Ingestion
Do NOT induce vomiting. Get medical attention.
Most important symptoms and effects
No information available.
SECTION 5. FIREFIGHTING MEASURES
Suitable Extinguishing Media
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Unsuitable
Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
Non-combustible. Do not allow run-off from fire-fighting to enter drains or water courses. Hazardous
Combustion Products
Hydrogen halides.
Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
equivalent) and full protective gear.
NFPA
Health
2
Flammability
Instability
1
Physical hazards
N/A
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Ensure adequate ventilation. Use personal protective equipment as required.
Environmental Precautions
Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground
water system. Prevent product from entering drains. Local authorities
should be advised if significant spillages cannot be contained.
Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal. Do not let this chemical enter the
environment.
SECTION 7. HANDLING AND STORAGE
Handling
Avoid contact with skin and eyes. Do not breathe dust. Do not ingest. If swallowed then
seek immediate medical assistance.
Storage
Keep in a dry, cool and well-ventilated place. Refer product specification and/or pro
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
This product does not contain any hazardous materials with occupational exposure limits established
by the region specific regulatory bodies.
Engineering Measures
Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations
and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/face Protection
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State Solid
Appearance Reddish violet
Odor No information available
Odor Threshold No information available
pH No information available
Melting Point/Range No data available
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula Br2 Co . x H2 O
Molecular Weight 218.75
SECTION 10. STABILITY AND REACTIVITY
Reactive Hazard None known, based on information available
Stability Stable. Hygroscopic.
Conditions to Avoid Incompatible products. Exposure to moist air or water.
Incompatible Materials Strong oxidizing agents, Metals
Hazardous Decomposition Products Hydrogen halides
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information
Oral LD50 Category 4. ATE = 300 - 2000 mg/kg. Dermal LD50 Category 4. ATE = 1000 - 2000 mg/kg.
Mist LC50 Category 4. ATE = 1 - 5 mg/l. Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation Irritating to eyes, respiratory system and skinSensitization No information available
Mutagenic Effects No information available
Reproductive Effects No information available. Developmental Effects No information available.
Teratogenicity No information available. STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and
delayed
No information available
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The
product contains following substances which are hazardous for the environment.
Persistence and Degradability Soluble in water
Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
SECTION 14. TRANSPORT INFORMATION
DOT
UN-No UN3077
Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. Hazard Class 9
Packing Group III
TDG
UN-No UN3077
Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. Hazard Class 9
Packing Group III
IATA
UN-No UN3077
Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.* Hazard
Class 9
Packing Group III
IMDG/IMO
UN-No UN3077
Proper Shipping Name Environmentally hazardous substances, solid, n.o.s. Hazard Class 9
Packing Group III
SECTION 15. REGULATORY INFORMATION
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
OSHA - Occupational Safety and Health Administration Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals. Other International Regulations
Mexico - Grade No information available.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
