SECTION 1. IDENTIFICATION
Product Name: Ferrosilicon
CAS #: 8049-17-0
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
2.1 Classification Of The Substance Or Mixture
2.1.1 Classification according to Regulation (EC) No. 1272/2008 (CLP)
The product is not classified as hazardous according to the Globally Harmonized System (GHS).
The substance is not classified as hazardous according to the CLP regulation.
2.1.2 Classification according to Directive 67/548/EEC & Directive 1999/45/EC – N/A
Information concerning particular hazards for human and environment:
The product does not have to be labelled due to the calculation procedure of the “General
Classification
guideline for preparations of the EU” in the latest valid version.
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature
data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
2.2 Label Elements
2.2.1 Label Elements According to Regulation (EC) No. 1272/2008 (CLP)
This product does not have a classification according to the CLP regulation.
The product is not classified as hazardous according to OSHA GHS regulations within the United
States.
HazardPictogram(s)
Not regulated Signal
Word(s)
Not regulated
Hazard-determining components of labelling: None
Hazard
Statement(s)
Not regulated
Hazard description:
WHMISsymbols:
None
NFPA ratings
(scale 0 - 4)
Health = 0
Fire = 0
Reactivity = 0
HMIS-ratings
(scale 0 - 4)
Health = 0
Fire = 0
Reactivity = 0
HMIS Long
Term Health
Hazard
Substances
Substance is not listed
2.3 Other Hazards
Results of PBT
and vPvB
assessment
PBT: N/A
vPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
CAS # / Substance Name
8049-17-0 Ferrosilicon
Identification number(s)
EC number: 617-088-7
SECTION 4. FIRST AID MEASURES
4.1 Description of First Aid Measures
General Information: No special measures required.
If inhaled: Supply fresh air; consult doctor in case of complaints.
In case of skin contact: Brush off loose particles from skin. Wash with soap and water. If skin irritation
is
experienced, consult a doctor.
In case of eye contact: Remove contact lenses if worn. Rinse opened eye for several minutes under
running water. If symptoms persist, consult a doctor.If swallowed: Rinse out mouth and then drink plenty of water. Do not induce vomiting; call for
medical help immediately.
4.2 Most Important
Symptoms And
Effects, Both Acute
And Delayed
Slight irritant effect on eyes. Gastric or intestinal disorders when ingested. Nausea in
case of ingestion.
Hazards No data available
4.3 Indication Of The
Immediate Medical
Attention And Special
Treatment Needed
No data available
SECTION 5. FIREFIGHTING MEASURES
5.1 Extinguishing Media
Suitable Extinguishing
Media
Use fire extinguishing methods suitable to surrounding conditions.
Unsuitable Extinguishing
Media
None.
5.2 Special Hazards Arising
From The Substance Or
Mixture
No data available
5.3 Advice for Fire-Fighters Wear self-contained respiratory protective device. Wear fully protective
suit.
Additional Information No data available
SECTION 6. ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions,
Protective Equipment And
Emergency Procedures
Avoid formation of dust. For large spills, use respiratory protective
device against the effects of fumes/dust/aerosol. For large spills, wear
protective clothing. Ensure adequate ventilation.
6.2 Environmental Precautions Do not allow to enter sewers/ surface or groundwater.
6.3 Methods And Material For
Containment And Cleaning Up
Pick up mechanically. Dispose contaminated material as waste
according to item 13.
6.4 Reference To Other Sections See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
7.1
Precautions For Safe
Handling
Use only in well ventilated areas. Prevent formation of dust. Do not dry clean dust
covered objects and floors. Wash thoroughly with plenty of water. Any unavoidable
deposit of dust must be regularly removed.
Information About
Fire – and explosion
protection
No special measures required.
7.2 Conditions For Safe Storage, Including Any Incompatibilities:
Requirements to be
Met by Storerooms
and Receptacles:
Store in a cool location. Protect from humidity and water.
Information About
Storage in One
Common Storage
Facility:
Store away from oxidizing agents. Store away from foodstuffs. Do not store together
with acids.
Further information
about storage
conditions:
Store in cool, dry conditions in well sealed receptacles.
7.3 Specific End Use(s) No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical facilities: No further data; see item 7.
8.1 Control Parameters
Ingredients with limit values that require monitoring at the workplace:
Ferrosilicon 8049-17-0 PEL (USA) Long-term value: 15 (total), 5 (resp.) mg/m3
DNELs No data available
PNECs No data available
Additional information: The lists valid during the making were used as basis.
8.2 Exposure Controls
8.2.2 Personal Protective Equipment:
General protective and hygienic measures:
General
protective and
hygienic
measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at
the end of work. Immediately remove all soiled and contaminated clothing. Do not
inhale dust / smoke / mist. Avoid contact with the eyes. Avoid close or long term
contact with the skin.
Respiratory
Protection
Not required under normal conditions of use. For spills, respiratory protection maybe advisable. Use suitable respiratory protective device when high concentrations
are present.
Eye Protection Wear safety glasses
Protection of
Hands
Wear protective gloves.
Body Protection Not required under normal conditions of use.
Protection may be required for spills.
Risk Management
Measures
No special requirements.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information On Basic Physical And Chemical Properties
Appearance Granulate Color Grey
Odor Odorless Odor Threshold (ppm) Not available
Melting Point (°C) /
Freezing Point (°C)
4892 °F/ 2700 °C Boiling Point/Boiling Range (°C) Not available
Flash Point (°C) No Data Explosive Limit Ranges Not available
Auto Ignition
Temperature (°C)
Not available Decomposition Temperature (°C) Not available
Explosive Properties None Oxidizing Properties Not available
Flammability (Solid, Gas) Not available Ph (Value) Not available
Evaporation Rate N/A Vapor Pressure (mm Hg) Not available
Vapor Density (Air=1) N/A Density (g/ml) 6,7 g/cm
3
Solubility (Water) Insoluble Solubility (Other) Not available
Partition Coefficient (NOctanol/
Water)
Not available Viscosity (mPa.s) Not available
9.2 Other Information Volatile Organic Chemical (VOC) Content – Not Available.
SECTION 10. STABILITY AND REACTIVITY
10.1 Reactivity
10.2 Chemical Stability
Thermal Decomposition / conditions
to be avoided:
No decomposition if used according to specifications.
10.3 Possibility of Hazardous Reactions Reacts with strong acids and alkali. Reacts with strong
oxidising agents.
10.4 Conditions To Avoid Store away from oxidsing agents. Moisture.
10.5 Incompatible Materials No data available
10.6 Hazardous Decomposition Product(s) Possible in traces.
SECTION 11. TOXICOLOGICAL INFORMATION
11.1 Information on Toxicological Effects
Primary Irritant Effect:
On the skin: Slight irritant effect on skin and mucous membranes.
On the eye: Slight irritant effect on eyes.
Sensitisation: No sensitizing effects known.
Additional toxicological
information:
When used and handled according to specifications, the
product does not have any harmful effects to our experience
and the information provided to us. The substance is not
subject to classification according to the latest version of the
EU lists.
Acute effects (acute toxicity,
irritation and corrosivity):
Inhalation may cause irritation to the respiratory system.
Repeated dose toxicity: Repeated exposure may result in skin sensitivity.
SECTION 12. ECOLOGICAL INFORMATION
12.1 Toxicity
Aquatic toxicity: No data available
12.2 Persistence and Degradability No data available
12.3 Bioaccumulative Potential No data available
12.4 Mobility in Soil No data available
Additional ecological information: Not known to be hazardous to water.
12.5 Results of PBT and vPvB
Assessment
PBT: N/A
vPvB: N/A
12.6 Other Adverse Effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Recommendation Smaller quantities can be disposed of with household waste. Contact waste
processors for recycling information. The user of this material has the
responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations
regarding treatment, storage and disposal for hazardous and nonhazardous
wastes. Residual materials should be treated as hazardous.
Uncleaned Packaging:
Recommendation: Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
Land Transport (ADR/RID) (c)(d) Land Transport (Within USA) (b)(d)
UN Number None UN Number None
Proper Shipping NameNot classified as
dangerous for transport.
Proper Shipping Name
Not classified as dangerous for
transport.
Transport Hazard Class(es) None Transport Hazard Class(es) None
Packing Group None Packing Group None
Hazard Label(s) None Hazard Label(s) None
Environmental Hazards None Environmental Hazards None
Special Precautions For User None Special Precautions For User None
Sea Transport (IMDG) (c) Air Transport (ICAO/IATA) (c) (d)
UN Number None UN Number None
Proper Shipping Name
Not classified as
dangerous for transport.
Proper Shipping Name
Not classified as dangerous for
transport.
Transport Hazard Class(es) None Transport Hazard Class(es) None
Packing Group None Packing Group None
Marine Pollutant None Marine Pollutant None
Special Precautions For User None Special Precautions For User None
(b)- ORM-D may be applicable within the USA for package sizes less than 30kg.
(c)– Consult with transport provider.
(d)– Check relevant regulations for Special Provisions.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
SECTION 15. REGULATORY INFORMATION
15.1 Safety, Health And Environmental Regulations/Legislation Specific For The Substance Or Mixture
USA
SARA
Section 355 (extremely hazardous
substances)
Substance is not listed.
Section 313 (Specific toxic chemical listings) Substance is not listed.
TSCA (Toxic Substance Control Act) Not all ingredients listed.
Proposition 65 (California):
Chemicals known to cause cancer: Substance is not listed.
Chemicals known to cause reproductive
toxicity for females:
Substance is not listed.
Chemicals known to cause reproductive
toxicity for males:
Substance is not listed.
Chemicals known to cause developmental
toxicity:
Substance is not listed.
Carcinogenic Categories
EPA (Environmental Protection Agency) Substance is not listed.
IARC (International Agency for Research on
Cancer)
Substance is not listed.TLV (Threshold Limit Value established by
ACGIH)
Substance is not listed.
MAK (German Maximum Workplace
Concentration)
Substance is not listed.
NIOSH-Ca (National Institute for
Occupational Safety and Health)
Substance is not listed.
Canada
Canadian Domestic Substances List (DSL) Substance is listed.
Canadian Ingredient Disclosure list (limit
0.1%)
Substance is not listed.
Canada Ingredient Disclosure list (limit 1%) Substance is listed.
Other regulations, limitations and prohibitive regulations
Substances of very high concern (SVHC)
according to REACH, Article 57
Substance is not listed.
15.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried
out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
