SECTION 1. IDENTIFICATION
Product Name: Barium Chromate
CAS #: 10294-40-3
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Oxidizing solids (Category 2), H272
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 4), H332
Carcinogenicity (Category 1B), H350
GHS Label elements, including precautionary statements
Pictogram
Signal word Danger
Hazard statement(s)
H272 May intensify fire; oxidizer.
H302 + H332 Harmful if swallowed or if inhaled.
H350 May cause cancer.
Precautionary statement(s)
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read andunderstood.
P210 Keep away from heat.
P220 Keep/Store away from clothing/ combustible materials.
P221 Take any precaution to avoid mixing with combustibles.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel
unwell. Rinse mouth.
P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER/doctor if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant
foam to extinguish.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal
plant.
Hazards not otherwise classified (HNOC) or not covered by GHS - none
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS No. / Substance Name:
10294-40-3 Barium chromate
Identification number(s):
EC number: 233-660-5
SECTION 4. FIRST AID MEASURES
Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed:
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the
surrounding fire.
For safety reasons unsuitable extinguishing agents Halocarbon extinguisher
Special hazards arising from the substance or mixture
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause
ignition.
If this product is involved in a fire, the following can be released:
Toxic metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow product to enter drains, sewage systems, or other water
courses.
Methods and materials for containment and cleanup:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
Acts as an oxidizing agent on organic materials such as wood, paper and fats
Keep away from combustible material.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
Substance/product can reduce the ignition temperature of flammable substances.
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause
ignition.
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Store away from flammable substances.
Store away from reducing agents.
Do not store with organic materials.Store away from metal powders.
Do not store together with acids.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Specific end use(s) No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
10294-40-3 Barium chromate (100.0%)
PEL (USA) Long-term value: 0.005* mg/m
3
Ceiling limit value: 0.1** mg/m
3
*as Cr(VI) **as CrO3; see 29 CFR 1910.1026
REL (USA) Long-term value: 0.001 mg/m
3
as Cr; See Pocket Guide Apps. A and C
TLV (USA) Long-term value: 0.01 mg/m
3
as Cr
EL (Canada) Short-term value: C0.1 mg/m
3
Long-term value: 0.025 mg/m
3
as Cr; ACIGH A1, IARC 1
Ingredients with biological limit values:
10294-40-3 Barium chromate (100.0%)
BEI (USA) 25 μg/L
Medium: urine
Time: end of shift at end of workweek
Parameter: Total chromium (fume)
10 μg/L
Medium: urine
Time: increase during shift
Parameter: Total chromium (fume)
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls.
Risk assessment should be performed to determine if airpurifying
respirators are appropriate. Only use equipment tested and approved under appropriate government
standards.
Protection of hands:
Impervious glovesInspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary
from manufacturer to manufacturer.
Material of gloves Polyvinyl chloride (PVC)
Penetration time of glove material (in minutes) No data available
Eye protection: Safety glasses
Body protection: Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: Yellow
Odor: Odorless
Odor threshold: No data available.
pH: N/A
Melting point/Melting range: No data available
Boiling point/Boiling range: No data available
Sublimation temperature / start: No data available
Flammability (solid, gas) Contact with combustible material may cause fire.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: N/A
Density at 20 °C (68 °F): 4.5 g/cm
3
(37.553 lbs/gal)
Relative density No data available.
Vapor density N/A
Evaporation rate N/A
Solubility in / Miscibility with
Water: Insoluble
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A
Kinematic: N/A
Other information No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity May intensify fire; oxidizer.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored
according to specifications.
Possibility of hazardous reactions
Reacts with reducing agents
Reacts with flammable substances
Conditions to avoid No data availableIncompatible materials:
Acids
Flammable substances
Reducing agents
Organic materials
Metal powders
Hazardous decomposition products: Toxic metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
Harmful if inhaled.
Harmful if swallowed.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: May cause an allergic skin reaction.
Germ cell mutagenicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains
mutation data for this substance.
Carcinogenicity:
May cause cancer.
IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity.
ACGIH A1: Confirmed human carcinogen: Agent is carcinogenic to humans based on epidemiologic
studies of, or convincing clinical evidence in, exposed humans.
NTP-K: Known to be carcinogenic: sufficient evidence from human studies.
(inhalation) EPA-A: human carcinogen: sufficient evidence from epidemiologic studies to support a
causal association between exposure and cancer.
(inhalation) EPA-K: Known human carcinogens.
(oral) EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of
carcinogenicity or no data are available.
(oral) EPA-CBD: Carginogenic potential cannot be determined.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: No effects known.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this
substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Ecotoxical effects:
Remark: Very toxic for aquatic organisms
Additional ecological information:
Do not allow product to reach groundwater, water courses, or sewage systems, even in smallquantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Very toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA UN1479
UN proper shipping name
DOT Oxidizing solid, n.o.s. (Barium chromate)
IMDG, IATA OXIDIZING SOLID, N.O.S. (Barium chromate)
Transport hazard class(es)
DOT
Class 5.1 Oxidising substances.
Label 5.1
Class 5.1 (O2) Oxidizing substances
Label 5.1
IMDG, IATA
Class 5.1 Oxidising substances.
Label 5.1
Packing group
DOT, IMDG, IATA III
Environmental hazards: N/A
Special precautions for user Warning: Oxidizing substances
EMS Number: F-A,S-Q
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
UN "Model Regulation": UN1479, Oxidizing solid, n.o.s. (Barium chromate), 5.1, III
SECTION 15. REGULATORY INFORMATION
SARA 302 Components
This material does not contain any components with a section 302 EHS TPQ.
SARA 313 ComponentsThe following components are subject to reporting levels established by SARA Title III,
Section 313:
Barium chromate
CAS-No.
10294-40-3
Revision Date
2007-03-01
SARA 311/312 Hazards
Reactivity Hazard, Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
