CD2152 Cadmium Oxide Powder (CAS No. 1306-19-0)

SECTION 1. IDENTIFICATION

Product Name: Cadmium Oxide

CAS #: 1306-19-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

GHS06 Skull and crossbones

Acute Tox. 2 H330 Fatal if inhaled.

GHS08 Health hazard

Muta. 2 H341 Suspected of causing genetic defects.

Carc. 1B H350 May cause cancer.

Repr. 2 H361 Suspected of damaging fertility or the unborn child.

STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.

Hazards not otherwise classified

No data available

Label elements

Labelling according to Regulation (EC) No 1272/2008

The substance is classified and labeled according to the CLP regulation.

Hazard pictograms

GHS06 GHS08Signal word: Danger

Hazard statements

H330 Fatal if inhaled.

H341 Suspected of causing genetic defects.

H350 May cause cancer.

H361 Suspected of damaging fertility or the unborn child.

H372 Causes damage to organs through prolonged or repeated exposure.

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapors/spray.

P284 Wear respiratory protection.

P281 Use personal protective equipment as required.

P320 Specific treatment is urgent (see on this label).

P405 Store locked up.

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

WHMIS classification

D1A - Very toxic material causing immediate and serious toxic effects

D2A - Very toxic material causing other toxic effects

Classification system

HMIS ratings (scale 0-4)

(Hazardous Materials Identification System)

HEALTH

FIRE

REACTIVITY

3

0

1

Health (acute effects) = 3

Flammability = 0

Physical Hazard = 1

Other hazards

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

CAS No. / Substance Name:

1306-19-0 Cadmium oxide

Identification number(s):

EC number: 215-146-2

Index number: 048-002-00-0

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General information

Immediately remove any clothing soiled by the product.

Remove breathing apparatus only after contaminated clothing has been completely removed.

In case of irregular breathing or respiratory arrest provide artificial respiration.If inhaled:

Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.

Seek immediate medical advice.

In case of skin contact:

Immediately wash with soap and water; rinse thoroughly.

Seek immediate medical advice.

In case of eye contact:

Rinse opened eye for several minutes under running water. Consult a physician.

If swallowed:

Seek medical treatment.

Information for doctor

Most important symptoms and effects, both acute and delayed

No data available

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing agents

Product is not flammable. Use fire-fighting measures that suit the surrounding fire.

Special hazards arising from the substance or mixture

If this product is involved in a fire, the following can be released:

Cadmium oxide

Advice for firefighters

Protective equipment:

Wear self-contained respirator.

Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Keep unprotected persons away.

Ensure adequate ventilation

Environmental precautions:

Do not allow product to enter drains, sewage systems, or other water courses.

Methods and materials for containment and cleanup:

Dispose of contaminated material as waste according to section 13.

Ensure adequate ventilation.

Prevention of secondary hazards:

No special measures required.

Reference to other sections

See Section 7 for information on safe handling

See Section 8 for information on personal protection equipment.

See Section 13 for disposal information.

SECTION 7. HANDLING AND STORAGE

Handling

Precautions for safe handlingKeep container tightly sealed.

Store in cool, dry place in tightly closed containers.

Ensure good ventilation at the workplace.

Open and handle container with care.

Information about protection against explosions and fires:

The product is not flammable

Conditions for safe storage, including any incompatibilities

Requirements to be met by storerooms and receptacles:

No special requirements.

Information about storage in one common storage facility:

Store away from magnesium/magnesium alloys

Further information about storage conditions:

Keep container tightly sealed.

Store in cool, dry conditions in well-sealed containers.

Specific end use(s)

No data available

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:

Properly operating chemical fume hood designed for hazardous chemicals and having an average

face velocity of at least 100 feet per minute.

Control parameters

Components with limit values that require monitoring at the workplace:

1306-19-0 Cadmium oxide (100.0%)

PEL (USA) Long-term value: 0.005 mg/m

3

as Cd; see 29 CFR 1910.1027

REL (USA) See Pocket Guide App. A

TLV (USA) Long-term value: 0.01 0.002* mg/m

3

as Cd; *respirable fraction; BEI

EL (Canada) Long-term value: 0.01 mg/m

3

as Cd; ACIGH A1, IARC 1

Additional information: No data

Exposure controls

Personal protective equipment

Follow typical protective and hygienic practices for handling chemicals.

Keep away from foodstuffs, beverages and feed.

Remove all soiled and contaminated clothing immediately.

Wash hands before breaks and at the end of work.

Store protective clothing separately.

Maintain an ergonomically appropriate working environment.

Breathing equipment:

Use self-contained respiratory protective device in emergency situations.

Recommended filter device for short term use:

Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls.

Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only

use equipment tested and approved under appropriate government standards.

Protection of hands: Impervious gloves

Inspect gloves prior to use.

Suitability of gloves should be determined both by material and quality, the latter of which may vary by

manufacturer.

Material of gloves

Nitrile rubber, NBR

Penetration time of glove material (in minutes): No data available

Eye protection: Safety glassesBody protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance:

Form: Powder or solid in various forms

Color: Red-brown

Odor: Odorless

Odor threshold: No data available.

pH: N/A

Melting point/Melting range: 1430 °C (2606 °F)

Boiling point/Boiling range: No data available

Sublimation temperature / start: 1559 °C (2838 °F)

Flammability (solid, gas): No data available.

Ignition temperature: No data available

Decomposition temperature: No data available

Autoignition: No data available.

Danger of explosion: No data available.

Explosion limits:

Lower: No data available

Upper: No data available

Vapor pressure: N/A

Density at 20 °C (68 °F): 8.15 g/cm

3

(68.012 lbs/gal)

Relative density: No data available.

Vapor density: N/A

Evaporation rate: N/A

Solubility in Water (H

2

O): Insoluble

Partition coefficient (n-octanol/water): No data available.

Viscosity:

Dynamic: N/A

Kinematic: N/A

Other information

No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Thermal decomposition / conditions to be avoided:

Decomposition will not occur if used and stored according to specifications.

Possibility of hazardous reactions

No dangerous reactions known

Conditions to avoid

No data available

Incompatible materials:

Magnesium/magnesium alloys

Hazardous decomposition products:

Cadmium oxide

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity: Fatal if inhaled.

The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this

substance.

LD/LC50 values that are relevant for classification:

Oral LD50 72 mg/kg (rat)

Inhalative LC50/1H 45 mg/m3/1H (rat)

Skin irritation or corrosion: May cause irritation

Eye irritation or corrosion: May cause irritation

Sensitization: No sensitizing effects known.

Germ cell mutagenicity: Suspected of causing genetic defects.

Carcinogenicity: May cause cancer.

IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity.

EPA-B1: Probable human carcinogen, limited evidence of carcinogenicity from epidemiologic studies.

Carcinogen as defined by OSHA.

ACGIH A2: Suspected human carcinogen: Agent is carcinogenic in experimental animals at dose

levels, by route(s) of administration, at site(s), of histologic type(s), or by mechanism(s) considered

relevant to worker exposure. Available epidemiologic studies are conflicting or insufficient to confirm

an increased risk of cancer in exposed humans.

NTP-K: Known to be carcinogenic: sufficient evidence from human studies.

The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or

carcinogenic and/or neoplastic data for this substance.

Reproductive toxicity:

Suspected of damaging fertility or the unborn child.

The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this

substance.

Specific target organ system toxicity - repeated exposure:

Causes damage to organs through prolonged or repeated exposure.

Specific target organ system toxicity - single exposure: No effects known.

Aspiration hazard: No effects known.

Subacute to chronic toxicity:

The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for

this substance.

Additional toxicological information:

To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

Carcinogenic categories

OSHA-Ca (Occupational Safety & Health Administration)

Substance is listed.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity:

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soilNo data available

Ecotoxical effects:

Remark:

Very toxic for aquatic organisms

Additional ecological information:

Do not allow product to reach groundwater, water courses, or sewage systems, even in small

quantities.

Danger to drinking water if even extremely small quantities leak into the ground.

Also poisonous for fish and plankton in water bodies.

May cause long lasting harmful effects to aquatic life.

Avoid transfer into the environment.

Very toxic for aquatic organisms

Results of PBT and vPvB assessment

PBT: N/A

vPvB: N/A

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Recommendation

Consult official regulations to ensure proper disposal.

Uncleaned packagings:

Recommendation:

Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

DOT (US)

UN number: 2570

Class: 6.1

Packing group: I

Proper shipping name: Cadmium compounds (Cadmium oxide non-pyrophoric)

Reportable Quantity (RQ):

Poison Inhalation Hazard: No

IMDG

UN number: 2570

Class: 6.1

Packing group: I

EMS-No: F-A, S-A

Proper shipping name: CADMIUM COMPOUND (Cadmium oxide non-pyrophoric)

IATA

UN number: 2570

Class: 6.1

Packing group: I

Proper shipping name: Cadmium compound (Cadmium oxide non-pyrophoric)

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations

All components of this product are listed in the U.S. Environmental Protection Agency Toxic

Substances Control Act Chemical substance Inventory.

All components of this product are listed on the Canadian Domestic Substances List (DSL).

SARA Section 313 (specific toxic chemical listings)

1306-19-0 Cadmium oxide

California Proposition 65

Prop 65 - Chemicals known to cause cancer

1306-19-0 Cadmium oxide

Prop 65 - Developmental toxicity

Substance is not listed.

Prop 65 - Developmental toxicity, female

Substance is not listed.

Prop 65 - Developmental toxicity, male

Substance is not listed.

Information about limitation of use:

Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the

authorities in certain cases.

For use only by technically qualified individuals.

Other regulations, limitations and prohibitive regulations

Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.

This substance is included in the Candidate List of Substances of Very High Concern (SVHC)

according to Regulation (EC) No. 1907/2006 (REACH).

The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No

1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.

Substance is not listed.

Annex XIV of the REACH Regulations (requiring Authorisation for use)

Substance is not listed.

Chemical safety assessment:

A Chemical Safety Assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.